光子学报, 2021, 50 (1): 45, 网络出版: 2021-03-12  

二维光催化材料的电子结构调控与应用研究进展(特邀) 下载: 991次

Progress on Electronic Structure Control and Application of Two Dimensional Photocatalytic Materials (Invited)
作者单位
延安大学 化学与化工学院 延安市新能源新功能材料重点实验室,陕西省化学反应工程重点实验室,陕西延安716000
摘要
首先综述了基于二维光催化剂的电子结构调控方式,包括厚度调节、元素掺杂、缺陷工程和异质结的设计等。其次,由于半导体异质结在减少光生电子空穴复合速度方面具有独特的优势,着重介绍了由二维材料与其它不同维数的半导体界面组成的异质结的研究进展。最后介绍了新型二维光催化材料在析氢、CO2还原、固氮和污染物降解等方面的应用。总结文献可知,二维材料与块体材料相比,具有较高的比表面积、表面存在大量的活性位点、能更有效地分离催化剂中的载流子、合适的能带结构、可调节的光吸收区等特点。文末总结了目前的研究现状和面临的挑战,并展望了二维材料在光催化中的应用前景。
Abstract
Firstly, the electronic structure control methods of photocatalysts based on two dimensional (2D) materials are briefly reviewed, including thickness control, element doping, defect engineering and heterojunction design, etc. Secondly, it is mainly introduced that the research progress of heterogeneous junctions composed of 2D materials and other semiconductor interfaces with different dimensions due to the unique advantages of heterogeneous junctions in reducing the rate of photoelectron hole recombination. Then the applications of new 2D photocatalytic materials in hydrogen evolution, CO2 reduction, nitrogen fixation and pollutant degradation are introduced. It is shown that, compared with bulk materials, 2D materials have higher specific surface area, a large number of active sites on the surface, more effective separation of carriers in the catalyst, appropriate energy band structure, and adjustable light absorption zone, etc. At last the current research status and challenges are briefly summarized, and the prospect of application of 2D materials in photocatalysis is prospected .

张文林, 许春花, 孙萌飞, 王羽龙, 李然, 张玉琦, 王记江. 二维光催化材料的电子结构调控与应用研究进展(特邀)[J]. 光子学报, 2021, 50(1): 45. Wenlin ZHANG, Chunhua XU, Mengfei SUN, Yulong WANG, Ran LI, Yuqi ZHANG, Jijiang WANG. Progress on Electronic Structure Control and Application of Two Dimensional Photocatalytic Materials (Invited)[J]. ACTA PHOTONICA SINICA, 2021, 50(1): 45.

引用该论文: TXT   |   EndNote

相关论文

加载中...

关于本站 Cookie 的使用提示

中国光学期刊网使用基于 cookie 的技术来更好地为您提供各项服务,点击此处了解我们的隐私策略。 如您需继续使用本网站,请您授权我们使用本地 cookie 来保存部分信息。
全站搜索
您最值得信赖的光电行业旗舰网络服务平台!