脉冲法磷光寿命测量中,激发光脉冲参量(脉冲宽度和形状)、用于磷光强度衰减分析的起始时刻的选取是影响寿命计算准确度的关键因素.以线性时不变系统理论为依据,探讨了磷光强度衰减特性与激发光脉冲参量之间的关系,发现对于有限宽度的激发光,激发光脉冲消失之后的磷光强度衰减特性独立于激发光脉冲参量;选取激发光脉冲消失时刻作为磷光强度衰减分析的起始时刻,可获得准确的寿命计算.利用磷光探针氧卟啉(Oxy-Phor R2)标准试样做了针对性实验,实验结果验证了理论的正确性.

In the phosphorescence lifetime measurements with pulse method, both the excitation light pulse parameters and initial time selected for intensity decay analysis are crucial to the accurate lifetime calculation. The relation between phosphorescence intensity decay and the parameters of the excitation light pulse is analyzed based on the linear time invariance. it is found that the phosphorescence intensity decay is independent on the parameters of the excitation light pulse after the excitation light vanishing. If the excitation light pulse vanishing moment is selected as the initial time, the accurate lifetime can be obtained. The experimental results from the Oxy-Phor R2 samples excited by different excitation light pulse have proved the above conclusion.