原子与分子物理学报, 2004, 21 (3): 441, 网络出版: 2006-06-11
类铍离子激发态的能量计算
The energy calculation of the excited state for berylliumlike ions
摘要
采用多组态相互作用方法及Rayleigh-Ritz变分法,计算了类铍O4+离子1s22s2p3P°态的非相对论能量,并详细分析了如何选择质量最好的变分波函数。运用截断变分方法进一步饱和函数空间得到能量的改进量,并考虑相对论修正、质量极化效应等获得了相对论能量计算值。计算结果表明,此理论计算方法可得到高精度的能量计算值。
Abstract
The Rayleigh-Ritz variational calculation is carried out with a multiconfiguration-interraction wave function on the excited state 1s22s2p3P° in berylliumlike O4+. Choosing the basis function with sufficiently high quality get the energy Eb. A restricted variation method is used to extrapolate a better nonrelativistic energy. The relativistic corrections and mass polarization are included. The results are better than other theoretical and agreement with experimental data.
韩利红, 张茹. 类铍离子激发态的能量计算[J]. 原子与分子物理学报, 2004, 21(3): 441. 韩利红, 张茹. The energy calculation of the excited state for berylliumlike ions[J]. Journal of Atomic and Molecular Physics, 2004, 21(3): 441.