光学学报, 2007, 27 (1): 119, 网络出版: 2007-01-22   

掺杂Ag纳米粒子对偶氮聚合物光致异构效应的影响

Influence of Silver-Doped Nanoparticles on Photo-Induced Isomerization of Azo Polymer
作者单位
1 中国科学技术大学精密机械与精密仪器系, 合肥 230027
2 中国科学技术大学高分子科学与工程系, 合肥 230027
摘要
报道了通过宏观测量偶氮聚合物光致异构效应, 及其引起的光学各向异性变化, 讨论了一种影响偶氮聚合物顺反异构效应的有效途径。在偶氮高分子聚合物中, 添加了不同浓度的Ag纳米粒子, 采用了波长为442 nm的He-Cd偏振激光为激发光源, 当Ag纳米粒子掺杂质量浓度为0.12 μg/ml的时候, 激发了薄膜样品中Ag纳米粒子的等离子体共振效应, 增强了粒子周围纳米尺度的电磁场强度, 相当程度上提高了偶氮聚合物光致异构的转换效率; 另外, 研究了不同的取代基同纳米Ag粒子的相互作用对光致异构效应的影响, 探讨了一种能够有效地控制光致异构效应的方法。
Abstract
The optical anisotropy caused by photo-induced isomerization of azo polymer has been investigated by experimental measurement. And a method to influence the photo-induced isomerization of azo polymer has also been reported. Silver nanoparticles with different spacing distances have been doped into the azo polymer, and the He-Cd laser with wavelength 442 nm has been used to excite the plasmon resonance effect of the silver nanoparticles. The intensity of electromagnetic field around the nano-particles has been enhanced while the mass concentration of Ag is 0.12 μg/ml and the plasmon resonance of silver nanoparticles in the thin sample is triggered. The conversion efficiency of photo-induced isomerization is also advanced greatly. In addition, we changed the mesogenic side groups of azo polymer and investigated the influence of interaction between mesogenic side groups and silver nanoparticles on the photo-induced isomerization. And a method to efficiently control the photo-induced isomerization effect has been presented.

杨建军, 周京利, 王克逸, 张其锦. 掺杂Ag纳米粒子对偶氮聚合物光致异构效应的影响[J]. 光学学报, 2007, 27(1): 119. 杨建军, 周京利, 王克逸, 张其锦. Influence of Silver-Doped Nanoparticles on Photo-Induced Isomerization of Azo Polymer[J]. Acta Optica Sinica, 2007, 27(1): 119.

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