光学学报, 1994, 14 (7): 692, 网络出版: 2007-08-17
纳米材料ZrO2的傅里叶变换红外光声光谱研究
Research on FT-IR-PAS Spectra of Nanocrystal ZrO2
单斜纳米ZrO2材料 傅里叶交换红外光声光谱(FT-IR-PAS) 量子尺寸效应 nanocrystalline monoclinic ZrO2 Fourier transform infrared photoacoustic spectros quantum size effect
摘要
首次报道单斜ZrO2纳米材料在各种微晶粒度下的傅里叶交换红外光声光谱(FT-IR-PAS),发现随着粒度的减小,波数低于1048 cm-1的谱线强度减弱,而波数高于1048 cm-1的话线强度增加,一些话线位置有红移,并观察了压力效应.对上述量子效应进行初步解释.
Abstract
It is reported for the first time that Fourier transform infrared photoacoustic spectroscopy (FT-IR-PAS) spectra of nanocrystalline monoclinic ZrO2 with different particle size. The results show that absorption intensities of Peaks below 1048 cm-l decrease, while those above 1048 cm-l increase. The POsition of some Peaks have red shift as decrease of particle size. Primary explanation is made for these quantum effects. The pressure effect is also observed.
刘方新, 胡克良, 王寅生, 刘方平. 纳米材料ZrO2的傅里叶变换红外光声光谱研究[J]. 光学学报, 1994, 14(7): 692. 刘方新, 胡克良, 王寅生, 刘方平. Research on FT-IR-PAS Spectra of Nanocrystal ZrO2[J]. Acta Optica Sinica, 1994, 14(7): 692.