Vibrational Raman and reflection spectra of 0. 1wt-% fullerene doped opticalglasses were investigated. Phosphate laser glass was used as matrix for fillerene dopant. Combbing with matrix Phosphate glass, the Raman active modes and the infrared reflectivecharacrteristics have been obviously changed in fullerene doped phosphate glass. This maysuggest the formation of some new molecules and network constructure in this fullerene dopedoptical glasses.