中国激光, 2007, 34 (s1): 36, 网络出版: 2009-05-25
激光引燃自蔓延合成Al-Ti-C中间合金差示扫描量热法分析
DSC Investigation on Self-Propagating High-Temperature Synthesis of AlTiC Master Alloy Induced by Laser
激光技术 自蔓延合成 中间合金 细化处理 差示扫描量热法热分析 laser technique self-propagating synthesis master alloys refining treatment differential scanning calorimetry analysis
摘要
利用元素间强烈的放热反应,采用激光引燃自蔓延Al-Ti-C合金合成铝合金晶粒细化中间合金。结果显示,所合成Al-50(TiC)中间合金内部作为异质核心的形核粒子TiC呈颗粒状,平均尺寸小于1 μm,粒子弥散分布,TiAl3呈长条状,中间合金加入铝熔体内,形核粒子较容易弥散开来。保温90 min未出现聚集成团现象,具有良好抗衰退能力。在所述实验条件下可使工业纯铝平均晶粒尺寸细化为150 μm以下,差示扫描量热法(DSC)热分析曲线出现一个尖锐的吸热峰和一个浑圆的放热峰。同时分析了激光引燃自蔓延合成的过程。
Abstract
Al-Ti-C refining master alloys, reaction among whose composing elements are exothermic, are fabricated by laser induced self-propagating high-temperature synthesis. Results show that TiC particles average size is less than 1 μm and distributes dispersedly and TiAl3 is strip-like in Al-50(TiC) master alloys. The master alloys have excelent refining efect on pure aluminium. The aluminium grain average size decreases to less than 150 μm after adding 0.1% the master alloys which have good resist-decline ability. There are a sharp endothermal peak and a obtuse exothermic peak on the differential scanning calorimetry (DSC) curve. The reaction process of self-propagating high-temperature synthesizing the master alloys is analyzed.
潘学民, 雷振坤, 王存山, 夏元化. 激光引燃自蔓延合成Al-Ti-C中间合金差示扫描量热法分析[J]. 中国激光, 2007, 34(s1): 36. 潘学民, 雷振坤, 王存山, 夏元化. DSC Investigation on Self-Propagating High-Temperature Synthesis of AlTiC Master Alloy Induced by Laser[J]. Chinese Journal of Lasers, 2007, 34(s1): 36.