强激光与粒子束, 2009, 21 (8): 1179, 网络出版: 2009-12-02
酸碱分步催化对溶胶-凝胶ZrO2薄膜光学性能的影响
Optical characterization of sol-gel ZrO2 coatings with acid alkali two-step method
摘要
以丙醇锆作为前驱体,利用酸碱分步催化法制备了ZrO2溶胶,用粒度仪检测胶体粒度;用N2 吸脱附表征凝胶的结构;采用旋转镀膜法在K9基片上镀制单层ZrO2薄膜;用分光光度计和椭偏仪检测膜层的透过率、折射率及膜层厚度;用红外光谱仪检测胶体内部粒子间化学键状态。实验结果发现,在脉宽1 nm,波长1 064 nm时,采用此种胶体镀制的单层ZrO2膜层折射率达到1.74,单层膜损伤阈值为9.0 J/cm2,表明该方法集中了酸与碱两种催化方式的优点,一定程度上提高了膜层的光学性能。
Abstract
A synthesis procedure of ZrO2 colloids derived from the acid-alkali two-step catalyzed hydrolysis was disclosed.The granularity and its distribution of the colloid particles were measured.Then a ZrO2 film was prepared by the spin-coating method on K9 glass.Physical properties of the thin film were characterized by ellipsometer,UV-Vis spectrophotometer,and Fourier transform infrared spectrometer.The refractive index of the coating with the two-step method was 1.74,and the laser damage threshold was 9.0 J/cm2 at 1 064 nm fundametal wavelength and 1 ns pulse duration.The measured and experimental results indicate that the two-step method have advantages over single step ones.
赵松楠, 吕海兵, 晏良宏, 王韬, 王海军, 袁晓东, 郑万国. 酸碱分步催化对溶胶-凝胶ZrO2薄膜光学性能的影响[J]. 强激光与粒子束, 2009, 21(8): 1179. Zhao Songnan, Lü Haibing, Yan Lianghong, Wang Tao, Wang Haijun, Yuan Xiaodong, Zheng Wanguo. Optical characterization of sol-gel ZrO2 coatings with acid alkali two-step method[J]. High Power Laser and Particle Beams, 2009, 21(8): 1179.