中国激光, 2010, 37 (8): 2063, 网络出版: 2010-08-13
衬底温度对脉冲激光沉积类金刚石薄膜的影响
Influence of the Substrate Temperature upon the Diamond-Like Carbon Films Deposited by Pulsed Laser
薄膜 类金刚石薄膜 脉冲激光沉积法 衬底温度 表面形貌 微观结构 sp3/ sp2比值 迁移 thin films diamond-like carbon film pulsed laser deposition substrate temperature topography microstructure ratio of sp3/sp2 transfer
摘要
中国科学院“计划”和合肥工业大学博士基金(GDBJ2008043)资助课题。
Abstract
The influence of the substrate temperature on the topography and microstructure of the diamond-like carbon (DLC) film in the pulsed laser deposition (PLD) is studied. When the diamond-like carbon films were deposited,the substrate temperature kept at 30,200,400 and 600 ℃ respectively. The microstructure and composition of the diamond-like carbon films deposited at different substrate temperatures were detected by the visible Raman spectroscopy and the X-ray photoelectron spectroscopy (XPS) respectively. The topography of the diamond-like carbon films was detected by the atomic force microscopy (AFM). The experimental result demonstrates that the substrate temperature influences microstructure,composition,ratio of sp3/sp2 and topography of the diamond-like carbon films in the pulsed laser deposition remarkably. When the substrate temperature increases,the ratio of sp3/sp2 in the film would decrease,the size and number of graphitic crystallites in the film would increase,the roughness of the film would reduce and the number of granules on the film would decrease. The reason to cause the experimental phenomenon is that transfer ability of the carbon ions and granules on the substrate would increase when the substrate temperature increases.
罗乐, 赵树弥, 仇冀宏, 方尚旭, 方晓东, 陶汝华. 衬底温度对脉冲激光沉积类金刚石薄膜的影响[J]. 中国激光, 2010, 37(8): 2063. Luo Le, Zhao Shumi, Qiu Jihong, Fang Shangxu, Fang Xiaodong, Tao Ruhua. Influence of the Substrate Temperature upon the Diamond-Like Carbon Films Deposited by Pulsed Laser[J]. Chinese Journal of Lasers, 2010, 37(8): 2063.