激光与光电子学进展, 2010, 47 (12): 121602, 网络出版: 2010-11-25
提高空气中制备Ba2MgSi2O7:Eu2+的发光性能
Enhanced Luminescence Properties of Ba2MgSi2O7:Eu2+ Prepared in Air Atmosphere
摘要
通过高温固相反应在空气中制备了一系列Eu掺杂的Ba2MgSi2O7发光材料。利用发射光谱和激发光谱,证实在Ba2MgSi2O7中,Eu3+在空气中被还原成Eu2+。研究表明:在1350 ℃急冷条件下制备Ba2MgSi2O7Eu2+荧光粉比在1250 ℃炉冷条件下制备的发光强度提高了近6倍。而且,添加NH4F助溶剂能提高空气中制备Ba2MgSi2O7Eu2+荧光粉的发光性能。当NH4F用量为4%时(摩尔分数),Ba2MgSi2O7Eu2+荧光粉的发光强度是不含助溶剂的5倍。
Abstract
A series of Eu-doped Ba2MgSi2O7 phosphors are prepared in air atmosphere by the high temperature solid-state reactions. A reduction of Eu3+ to Eu2+ ion is validated in Ba2MgSi2O7 via emission and excitation spectra measurement. The results show that the photoluminescence (PL) intensity of the Ba2MgSi2O7Eu2+ prepared in air at 1350 ℃ with quench cooling was enhanced about 6 times compared with that of Ba2MgSi2O7Eu2+ prepared in air at 1250 ℃ with furnace cooling. Moreover, the PL intensity of the Ba2MgSi2O7Eu2+ is increased by adding NH4F flux. The PL intensity of Ba2MgSi2O7Eu2+ phosphor containing 4% NH4F (molar fraction) is 5 times as high as that of the Ba2MgSi2O7Eu2+ phosphor without NH4F.
游潘丽, 刘丽娟, 姚亚东, 黄忠兵, 廖晓明, 尹光福. 提高空气中制备Ba2MgSi2O7:Eu2+的发光性能[J]. 激光与光电子学进展, 2010, 47(12): 121602. You Panli, Liu Lijuan, Yao Yadong, Huang Zhongbing, Liao Xiaoming, Yin Guangfu. Enhanced Luminescence Properties of Ba2MgSi2O7:Eu2+ Prepared in Air Atmosphere[J]. Laser & Optoelectronics Progress, 2010, 47(12): 121602.