光学学报, 2010, 30 (s1): s100102, 网络出版: 2010-12-13  

BaSi2O2N2:Eu2+荧光粉体的合成及发光性能研究

Synthesis and Luminescence Properties of Eu2+-Doped BaSi2O2N2 Phosphors
作者单位
中国计量学院材料科学与工程学院, 浙江 杭州 310018
摘要
采用超声波悬浮液法,合成了组成为Ba1-xSi2O2N2xEu2+(0.01≤x≤0.08)的蓝色荧光粉,用X射线衍射仪、荧光光谱仪分别对其结构及发光性能进行了表征。结果表明,这种荧光粉的主晶相是BaSi2O2N2Eu2+,在287~460 nm的宽波段范围内可以得到有效激发,发射出很强的蓝光。发射光谱显示出峰值在λ=487 nm的单峰宽带特征,这对应着Eu2+的4f65d→4f7跃迁, Eu2+在303 nm的波长激发下,由于无辐射弛豫现象,比在397 nm的波长激发下,有更大的斯托克斯位移。随着Eu2+浓度增加,发光强度也增加,发射峰红移,当x超过0.02时,出现浓度猝灭现象,发射强度逐渐减弱。在白光LED用荧光粉方面,这种新型蓝色荧光粉有广阔的应用前景。
Abstract
Blue-emitting Ba1-xSi2O2N2xEu2+(0.01≤x≤0.08) phosphor has been synthesized via an ultrasonic suspension route. The microstructure and photoluminescence properties of the as-synthesized phosphor are characterized by X-ray diffraction (XRD) and photoluminescence spectroscopy, respectively. Its XRD pattern indicates that the BaSi2O2N2Eu2+is the major crystalline phase for all compositions. It can be efficiently excited over a broad excitation band extending from 287 to 460 nm。The BaSi2O2N2Eu2+phosphor has strong blue emission. The emission spectrum consists of a single-peak broadband with a maximum at 487 nm, which may be ascribed to the 4f65d→4f7transition of Eu2+. A larger Stokes shift of Eu2+luminescence is expected at the excitation wavelength of 303 nm than at 397 nm due to nonradiative relaxation. The luminescence intensity is enhanced and a red shift is observed upon increasing Eu2+concentration. When x exceeds 0.02, the emission intensity tends to monotonically decrease due to the Eu2+concentration quenching. This new phosphor has promising applications in phosphor-converted white LED.

王倩, 华有杰, 苏醒宇, 李高峰, 邓德刚, 徐时清. BaSi2O2N2:Eu2+荧光粉体的合成及发光性能研究[J]. 光学学报, 2010, 30(s1): s100102. Wang Qian, Hua Youjie, Su Xingyu, Li Gaofeng, Deng Degang, Xu Shiqing. Synthesis and Luminescence Properties of Eu2+-Doped BaSi2O2N2 Phosphors[J]. Acta Optica Sinica, 2010, 30(s1): s100102.

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