光谱学与光谱分析, 2010, 30 (6): 1535, 网络出版: 2011-01-26
Ca2SrAl2O6荧光粉中Ce3+和Tb3+的光谱性能研究及能量传递
Spectral Properties and Energy Transfer of Ce3+ and Tb3+ Ions Co-Doped Ca2SrAl2O6 Phosphor
摘要
采用高温固相法合成了用于紫外芯片(UVLED)激发的绿色荧光粉Ca2SrAl2O6∶Ce3+, Tb3+。 测量了其激发光谱和发射光谱, 结果显示, 材料的发射谱由峰值位于497, 545, 595和623 nm的4组窄带组成, 其中位于545 nm的发射峰最强, 样品能发射很好的绿光; 监测545 nm发射峰, 得到的激发谱由位于320~400 nm之间的激发带组成, 能被UVLED很好地激发。 研究了Ca2SrAl2O6荧光粉中Ce3+对Tb3+发光的敏化现象, 发光的敏化作用缘于Ce3+和Tb3+之间的高效无辐射能量传递。 共掺激活剂的最佳掺杂浓度为4 mol%。
Abstract
Ce3+, Tb3+ co-doped green phosphor Ca2SrAl2O6 was synthesized by solid state method and its excitation and emission spectra were measured and studied. The results showed that the emission spectrum is composed of four groups of narrow bands and the peaks are located at 497, 545, 595 and 623 nm. The strongest emission peak islocated at 545 nm and chromaticity coordinate (x, y) is (0.300 5, 0.500 2) at 4 mol% Ce3+ and Tb3+ doping, which indicate that Ca2SrAl2O6∶Ce3+, Tb3+ was a good green phosphor. The excitation spectrum for 545 nm was in the region of 320-400 nm, which indicated that this phosphor could be effectively excited by UVLED. Duo to the overlap of the Ce3+ emission bands and the Tb3+ excitation bands, the energy transfer between Ce3+ and Tb3+ is expected to be very efficient. The emission intensity of co-doped Ca2SrAl2O6 phosphor was stronger than that of Tb3+ doped phosphor. The luminescence intensity reached the maximum when the concentration of Ce3+ and Tb3+ was 4 mol%.
李旭, 关丽, 刘冲, 杨志平, 郭庆林. Ca2SrAl2O6荧光粉中Ce3+和Tb3+的光谱性能研究及能量传递[J]. 光谱学与光谱分析, 2010, 30(6): 1535. LI Xu, GUAN Li, LIU Chong, YANG Zhi-ping, GUO Qing-lin. Spectral Properties and Energy Transfer of Ce3+ and Tb3+ Ions Co-Doped Ca2SrAl2O6 Phosphor[J]. Spectroscopy and Spectral Analysis, 2010, 30(6): 1535.