光谱学与光谱分析, 2011, 31 (6): 1518, 网络出版: 2012-01-05  

EVOH树脂薄膜制备及其保温性能的红外光谱研究

Preparation of EVOH Film and Infrared Spectroscopic Study of Its Heat Preservation Property
作者单位
1 北京理工大学理学院化学系, 北京 100081
2 北京华盾雪花塑料集团有限责任公司, 北京 100160
3 广东华南精细化工研究院, 广东 新会 529141
摘要
采用平挤上吹成膜工艺制备了EVOH, PE, EVA薄膜, 并利用红外光谱仪、 透光率/雾度测定仪等分别研究了以EVOH, PE, EVA树脂为基材生产的薄膜的透光率、 雾度、 红外阻隔率和温室增温、 保温性能的关系。 结果表明在光学性能上, EVOH树脂薄膜比常用的PE和EVA农膜的雾度分别下降10%和5%左右; 从红外透射率来看, EVOH薄膜的透射率较PE农膜和EVA农膜低很多, 尤其在辐射能量集中的7~14 μm波长范围内, EVOH的透射率仅为9.03%, 比EVA农膜低27%左右, 远远小于PE农膜, 说明其红外阻隔性能远远好于PE和EVA。 因此, EVOH薄膜的直射光透过率和红外阻隔效果更好, 作为农膜使用更有利于温室的升温和保温。
Abstract
EVOH, PE and EVA films were prepared by extrusive blowing techniques, the optic capability, transmittance, haze, infrared anti-transmittance and heat preservation of the films were studied by IR spectroscopy and optic block. The result indicated that the haze degree of the EVOH film decreased about 10% and 5% compared to PE film and EVA film respectively, EVOH film’s transmission of IR is much less than other films in the 2.5~25 μm wavelength range, it is just 9.03% in 7~14 μm wavelength range, and about 27% less than EVA film, while much less than PE film. It was found that EVOH film has much better capability of infrared anti-transmittance and point-blank light transmission than other two kinds of films. It was good for calefaction and heat preservation of greenhouse.

崔海龙, 王朝晖, 焦红文, 卢士香, 徐文国. EVOH树脂薄膜制备及其保温性能的红外光谱研究[J]. 光谱学与光谱分析, 2011, 31(6): 1518. CUI Hai-long, WANG Zhao-hui, JIAO Hong-wen, LU Shi-xiang, XU Wen-guo. Preparation of EVOH Film and Infrared Spectroscopic Study of Its Heat Preservation Property[J]. Spectroscopy and Spectral Analysis, 2011, 31(6): 1518.

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