Based on the theory of multicarrier(MC) technique and the Rake receiver, a multicarrier DS- CDMA Rake system is proposed, where a data sequence multiplied by a spreading sequence modulates multiple carriers. The receiver provides a Rake for each subcarrier, and the outputs of the Rakes are combined by a maximal-ratio combiner. The average probability of error of the system is derived from an uncorrelated subcarrier and frequency-selective fading channel model. The system performances are evaluated over Rayleigh fading channel with an exponential multipath intensity profile(MIP) and with a rectangular MIP, respectively, when multipath interference is present. It is found that this kind of model has larger superiority in an exponential MIP than in a rectangular MIP.