光学学报, 1986, 6 (2): 185, 网络出版: 2011-09-16
Na2O-Al2O3-B2O3-P2O5玻璃中铝和硼配位的Raman光谱研究
Raman spectroscopic study of coordinations of aluminium,boron in Na2O-Al2O3-B2O3-P2O5 glasses
摘要
利用Raman光谱技术研究了Na_2O-Al_2O_3-B_2O_3-P_2O_5玻璃中铝和硼的配位态.研究表明 当硼、铝共存于磷酸盐玻璃时,硼先于铝形成BO_4四面体.硼有3和4两种配位而铝有4和6两种配位.
Abstract
The coordination states of aluminium,boron in Na2O-Al2O3-BaO3-P2O5 glasses have been studied by means of Raman spectroscopy. The study shows that when boron,aluminium ions coexist in phosphate glasses, it is possible that boron iong form BO4 tetrahedra prior to aluminium ions, with the former having three or four coordinations,the latter having four or six.
金宜芬, 江德华, 陈祥生, 卞蓓亚, 黄熙怀. Na2O-Al2O3-B2O3-P2O5玻璃中铝和硼配位的Raman光谱研究[J]. 光学学报, 1986, 6(2): 185. JIN YIFEN, JIANG DEHUA, CHEN XIANGSHENG, BIAN BEIYA, HUANG XIHUAI. Raman spectroscopic study of coordinations of aluminium,boron in Na2O-Al2O3-B2O3-P2O5 glasses[J]. Acta Optica Sinica, 1986, 6(2): 185.
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