在室温情况下， 利用FTIR光谱仪测得了天然磁几何阻挫材料绿盐铜矿(Atacamite， β-Cu2(OH)3Cl)的中红外光谱4 000~400 cm-1， 同时还通过激光显微拉曼光谱仪获得了它的拉曼光谱4 000~95 cm-1。 结合它的晶体结构参数， 确认了官能团区4 000~2 500~1 000 cm-1和指纹区1 000~550~200~95 cm-1的特征峰以及探索它的微观起源。 将五个不同的区域分别指认为: 取决于羟基整体环境3Cu≡O—H…Cl的羟基伸缩振动νO—H4 000~2 500 cm-1； 由羟基弯曲振动模式基频所产生的泛频(合频或倍频)2 500~1 000 cm-1； 由δCu—O—H和δO—H…Cl组合的羟基弯曲振动模式δO—H 1 000~550 cm-1； 较强的键平面CuO4单元振动模式550~200 cm-1； 以及较弱的键线性三原子链Cl—Cu—O/Cl振动模式200~95 cm-1。 谱带指认时紧密结合晶体的结构参数， 从而较为合理建立了其分子结构和光谱特性之间的关系。

At room temperature, the mid-infrared spectra of geometrically frustrated natural atacamite (hydroxyl copper chloride, β-Cu2(OH)3Cl) in the range of 4 000~400 cm-1 were measured by FTIR spectrometers, and meanwhile its Raman spectrum in the range of 4 000~95 cm-1 was obtained by Jobin Yvon LabRAM HR800 Raman spectrometer. According to its crystal structure parameters, the authors confirmed the characteristic peaks of sample 4 000~2 500~1 000 cm-1 in the functional group region and 1 000~550~200~95 cm-1 in the fingerprint region, and also explored its microscopic origin. Five distinct regions were assigned: the hydroxyl stretching vibration νO—H determined by the overall environment around the hydroxyl group; the overtones generated by the sum or multiplication of fundamental frequencies of hydroxyl bending vibration; the hydroxyl bending vibration modes δO—H of the combination of δCu—O—H and δO—H…Cl; the vibration modes of strongly bonded planar CuO4 units; the vibration modes of weakly bonded linear-triatomic chain Cl—Cu—O/Cl. The bands were assigned in accordance with its crystal structure parameters, which is more reasonable to establish the relationship between its molecular structure and its respective spectral properties.