发光学报, 2011, 32 (12): 1210, 网络出版: 2012-01-04   

基于紫外或蓝光LED激发的Eu3+和Bi3+共掺杂LaMgB5O10红色荧光粉

Enhanced Red Photoluminescence in Eu3+ and Bi3+ Codoped LaMgB5O10 Based on UV/Blue LEDs Excitation
作者单位
大连海事大学 物理系, 辽宁 大连111026
摘要
采用固相法合成了Eu3+和Bi3+共掺杂的LaMgB5O10红色荧光粉,在紫外或蓝光激发下,样品的红光强度随着Bi2O3的增加而增强。利用X射线衍射对样品的结构进行了分析,结果表明,掺入Bi2O3后,样品的结晶度更好。根据Judd-Ofelt理论计算,得到样品的内量子效率不随掺杂剂的改变而变化,约为43%。在394 nm激发下,Eu3+和Bi3+共掺杂样品的红色荧光强度较Eu3+单掺杂样品中增强了50%。根据漫反射和变温光谱测量结果,分析指出Eu3+红色荧光增强是由于Eu3+的吸收增强。
Abstract
Red phosphors of Eu3+ and Bi3+ single- and double- doped LaMgB5O10 have been synthesized by a solid-state reaction. The red emission intensities were enhanced with the increase of Bi2O3 content. The crystal structures were analyzed using the X-ray diffraction. It indicated that the crystallization is better in the codoped samples than the Eu3+ monodoped sample. According to the results calculated by the Judd-Ofelt theory, the internal quantum efficiencies keep a constant value of about 43%. Moreover, red emission intensity increase 50% in the codoped sample comparison with the Eu3+ monodoped one under 394 nm excitation. It was confirmed that the enhanced red photoluminescence is due to the increase of Eu3+absorption strengths.

张金苏, 梁左秋, 仲海洋, 孙佳石, 程丽红, 李香萍, 陈宝玖. 基于紫外或蓝光LED激发的Eu3+和Bi3+共掺杂LaMgB5O10红色荧光粉[J]. 发光学报, 2011, 32(12): 1210. ZHANG Jin-su, LIANG Zuo-qui, ZHONG Hai-yang, SUN Jia-shi, CHENG Li-hong, LI Xiang-ping, CHEN Bao-jiu. Enhanced Red Photoluminescence in Eu3+ and Bi3+ Codoped LaMgB5O10 Based on UV/Blue LEDs Excitation[J]. Chinese Journal of Luminescence, 2011, 32(12): 1210.

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