采用高温熔融法制备了一系列Ce3+/Sm3+共掺透明微晶玻璃，并研究了其发光特性。在微晶玻璃中Ce3+呈现出基于4f-5d跃迁的较强的宽带蓝光发射，通过调节Ce3+/Sm3+离子的掺杂浓度，Ce3+/Sm3+离子共掺微晶玻璃发光的色度逐渐发生变化，当CeO2/Sm2O3掺杂的量比为1∶1时，制得的微晶玻璃发光色坐标为(0.315, 0.296)。通过光谱和荧光衰减曲线，研究了Ce3+离子到Sm3+离子的能量传递，在SAZKNGC0.6S0.6微晶玻璃中，Ce3+离子向Sm3+离子传递能量效率约为20%。结果表明,Ce3+/Sm3+共掺微晶玻璃是白光LED的一种潜在基质材料。

A series of transparent Ce3+/Sm3+ co-doped glass ceramics were prepared by high temperature melting, and their luminescence properties were studied. In the glass ceramics, Ce3+ ions have shown efficient broadband blue emission due to the 4f-5d transition, and Sm3+ ions have shown bright orange-red luminescence resulting from the 4G5/2→6HJ (J=5/2,7/2,9/2,11/2) transitions. By adjusting the doped concentration of Ce3+ and Sm3+ ions, the chroma of the samples varied gradually. When the mole fraction of CeO2 and Sm2O3 was 1∶1, the white light luminescence glass ceramic with the chromaticity coordinate (0.315, 0.296) was prepared. The energy transfer from Ce3+ to Sm3+ ions were investigated by spectra properties and fluorescence decay curves, energy transfer efficiency is about 20% in the SAZKNGC0.6S0.6 glass ceramics. The results indicate that Ce3+/Sm3+ co-doped glass ceramics containing β-Zn2SiO4 are potential matrix materials for white LEDs.