红外技术, 2012, 34 (5): 260, 网络出版: 2012-05-22  

射频磁控溅射氧化钒薄膜的结构与性能研究

Structure and Property Study on Vanadium Oxide Thin Films Deposited by Radio Frequency Magnetron Sputtering Technique
作者单位
1 昆明物理研究所,昆明 650223
2 中科院上海硅酸盐研究所,上海 200050
3 云南师范大学可再生能源先进材料与制备教育部重点实验室,昆明 650092
摘要
以非制冷微测辐射热计型红外探测器应用为需求背景,采用射频磁控溅射技术在 300℃低温条件下制备了氧化钒薄膜。采用 X射线衍射(XRD)、原子力显微镜(AFM)、能量色散谱(EDS)及 X射线光电子能谱(XPS)技术表征了薄膜的结晶状态、微观结构与化学组成。采用四探针技术研究了薄膜的电学性能。结果表明该薄膜主要为非晶态的二氧化钒(VO2),并具有光滑的表面形貌。这种非晶 VO2薄膜在 22~100℃温度范围内不存在半导体 -金属相变。 100 nm厚的非晶 VO2薄膜室温下的面电阻为 600 kΩ/□,同时表现出-2.1%/℃的较高电阻温度系数(TCR),这表明该薄膜有希望用于非制冷微测辐射热计型红外探测器。
Abstract
Aimed at uncooled microbolometer infrared detector applications, vanadium oxide thin films were fabricated successfully by the radio frequency magnetron sputtering technique at low temperature of 300℃. The crystalline, microstructure and composition of the films were characterized by X-ray diffraction (XRD), atomic force microscopy (AFM), energy-dispersive spectra (EDS) and X-ray photoelectron spectroscopy (XPS). The electric properties of the film were investigated using four-point probe technique. The results show that the film is VO2 phase and exhibits amorphous structure with smooth surface morphology. Semi-conductor-to-metal phase transition was not observed for such an amorphous VO2 thin film in the temperature range of 22-100℃. Moreover, excellent performances such as temperature coefficient of resistance (TCR) of -2.1%/℃ at room temperature and sheet resistance of 600 kΩ/square was obtained in the VO2 thin film with suitable thickness (100 nm), suggesting a potential application in uncooled microbolometer infrared detectors.

刘黎明, 莫镜辉, 史衍丽, 曾华荣, 杨培志. 射频磁控溅射氧化钒薄膜的结构与性能研究[J]. 红外技术, 2012, 34(5): 260. LIU Li-ming, MO Jing-hui, SHI Yan-li, ZENG Hua-rong, YANG Pei-zhi. Structure and Property Study on Vanadium Oxide Thin Films Deposited by Radio Frequency Magnetron Sputtering Technique[J]. Infrared Technology, 2012, 34(5): 260.

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