中国激光, 2012, 39 (s1): s106001, 网络出版: 2012-05-28
光吸收调制微加工技术中偶氮材料光吸收率的时间变化特性
Variation of Absorptivity with Time of Azo-Material in Absorbption Modulation Micro-Fabrication Technique
光学制造 偶氮苯光吸收率 时间变化特性 光致异构 optical fabrication optical absorptivity of azobenzene time dependence photo-isomerization
摘要
基于偶氮材料光吸收调制的高分辨率微加工技术近年来引起了极大关注。为揭示该技术中偶氮材料光吸收调制的机制,结合偶氮材料光致异构原理,利用偶氮材料的光吸收理论模型,数值模拟了偶氮材料光吸收率的时间变化特性。以典型偶氮苯染料分散黄7(Disperse Yellow 7-DY7)为例,分别开展了在365 nm光束单独作用和365 nm与532 nm双光束共同作用下,不同厚度DY7薄膜在365 nm光吸收率的时间变化特性实验研究。结果表明,在365 nm光束作用下,偶氮苯材料对365 nm光吸收率因光致异构效应发生了明显改变,而实验中532 nm光束的热效应对偶氮苯材料的光吸收率有显著的影响。
Abstract
The super-resolution micro-fabrication technique based on the optical absorption modulation of azo-material is attracting attentions for decades. To reveal the mechanism of the optical absorbance modulation of azo-material, the simulations of the variation of absorptivity with time are implemented based on the optical absorption model and the photo-isomerization principles of azo-material. Some membrane samples with different thicknesses are obtained by using a typical azobenzene dye [disperse yellow 7 (DY7)], and the experiment to study the variation of absorptivity with time of these samples is implemented, with 365 nm illumination only and 365 nm and 532 nm illumination together, respectively. The results indicate that the obsorptivity of azobenzene at 365 nm varies significantly due to the photo-isomerization of azobenzene, and it is influnced by the thermal effect due to 532 nm illumination.
黎达, 王曙, 赵星, 方志良, 袁小聪. 光吸收调制微加工技术中偶氮材料光吸收率的时间变化特性[J]. 中国激光, 2012, 39(s1): s106001. Li Da, Wang Shu, Zhao Xing, Fang Zhiliang, Yuan Xiaocong. Variation of Absorptivity with Time of Azo-Material in Absorbption Modulation Micro-Fabrication Technique[J]. Chinese Journal of Lasers, 2012, 39(s1): s106001.