光谱学与光谱分析, 2012, 32 (5): 1410, 网络出版: 2012-06-14  

改进型M-P神经网络在能量色散X荧光分析测定铅锌矿元素含量的应用研究

Research on the Application of Improved M-P Neural Network to the Determination of Lead and Zinc Ore Element Contents by Energy Disperse X-Ray Fluorescence Analysis
作者单位
成都理工大学, 四川 成都610059
摘要
以新疆西天山铅锌矿样品的Cu, Fe, Pb等元素X荧光测量数据做训练样本, McCulloch-Pitts神经网络(M-P神经网络)为基础, 基体效应为依据, 建立新的神经网络模型对Zn进行定量预测。 结果预测值与测量值的相对误差在<5%。 此方法可较准确, 快速的应用于现场X荧光测定, 为X荧光光谱信息修正提供一种新方法。
Abstract
Because of different constraints (such as different kinds of measurable elements, characteristic X-ray energy, changes in matrix composition, etc.), usually it’s not easy to get accurate information of elements, resulting in mistakes in later data analysis of energy disperse X-ray fluorescence measurement. The method is based on McCulloch-Pitts neural network (M-P neural network), according to matrix effect, to establish a new neural network model for quantitative forecasting of Zn by taking the data of X-ray fluorescence measurements of Cu, Fe, Pb, etc in lead-zinc mine in western Tianshan as the training sample. The relative error between predicted value and measured value is less than 5%. This method can be more accurate and rapid for X-ray fluorescence; it provides a new approach to correcting information of X-ray fluorescence.

李飞, 葛良全, 张庆贤, 谷懿, 万志雄, 李王燕. 改进型M-P神经网络在能量色散X荧光分析测定铅锌矿元素含量的应用研究[J]. 光谱学与光谱分析, 2012, 32(5): 1410. LI Fei, GE Liang-quan, ZHANG Qing-xian, GU Yi, WAN Zhi-xiong, LI Wang-yan. Research on the Application of Improved M-P Neural Network to the Determination of Lead and Zinc Ore Element Contents by Energy Disperse X-Ray Fluorescence Analysis[J]. Spectroscopy and Spectral Analysis, 2012, 32(5): 1410.

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