光谱学与光谱分析, 2013, 33 (1): 224, 网络出版: 2013-02-04   

ICP-OES/ICP-MS测定葵花子中28种无机元素

Study on the Determination of 28 Inorganic Elements in Sunflower Seeds by ICP-OES/ICP-MS
作者单位
1 湖南工学院材料与化学工程系, 湖南 衡阳421002
2 长江师范学院化学化工学院, 重庆408100
3 中国人民解放军军事经济学院, 湖北 武汉430035
摘要
建立了葵花子中微量元素组成的分析方法。 采用HNO3+H2O2混合酸为消解体系经微波消解葵花子样品, 电感耦合等离子体发射光谱(ICP-OES)法测定葵花子中Al, B, Ca, Fe, K, Mg, Na, Si, P和S, 电感耦合等离子体质谱(ICP-MS)法测定葵花子As, Ba, Cd, Co, Cr, Cu, Li, Mn, Mo, Ni, Pb, Rb, Sr, Sn, Sb, Ti, V和Zn。 采用国家一级标准物质大米(GBW10045)验证了方法的准确性, 结果表明, 标准物质的测定结果与参考值基本一致, 葵花子中Ca, K, Mg, P, S的含量较高。 该方法具有良好的准确性和精密度。
Abstract
The present paper describes a simple method for the determination of trace elements in sunflower seeds by using inductively coupled plasma optical emission spectrometry (ICP-OES) and inductively coupled plasma spectrometry (ICP-MS). HNO3+H2O2 were used to achieve the complete decomposition of the organic matrix in a closed-vessel microwave oven. The contents of 10 trace elements (Al, B, Ca, Fe, K, Mg, Na, Si, P and S) in sunflower seeds were determined by ICP-OES while 18 trace elements (As, Ba, Cd, Co, Cr, Cu, Li, Mn, Mo, Ni, Pb, Rb, Sr, Sn, Sb, Ti, V and Zn) were determined by ICP-MS. The rice reference material (GBW10045) was used as standard reference materials. The results showed a good agreement between measured and certified values for all analytes. The concentrations of necessary micro elements Ca, K, Mg, P and S were higher. This method was simple, sensitive and precise and can perform simultaneous multi-elements determination of sunflower seeds.

刘宏伟, 秦宗会, 谢华林, 曹恕. ICP-OES/ICP-MS测定葵花子中28种无机元素[J]. 光谱学与光谱分析, 2013, 33(1): 224. LIU Hong-wei, QIN Zong-hui, XIE Hua-lin, CAO Shu. Study on the Determination of 28 Inorganic Elements in Sunflower Seeds by ICP-OES/ICP-MS[J]. Spectroscopy and Spectral Analysis, 2013, 33(1): 224.

本文已被 2 篇论文引用
被引统计数据来源于中国光学期刊网
引用该论文: TXT   |   EndNote

相关论文

加载中...

关于本站 Cookie 的使用提示

中国光学期刊网使用基于 cookie 的技术来更好地为您提供各项服务,点击此处了解我们的隐私策略。 如您需继续使用本网站,请您授权我们使用本地 cookie 来保存部分信息。
全站搜索
您最值得信赖的光电行业旗舰网络服务平台!