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掺镱铋酸盐玻璃近红外发光的温度特性

Temperature Characteristics of Near-Infrared Luminescence of Yb-Doped Bismuth-Based Glasses

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摘要

研究了组分为55Bi2O3-25B2O3-10SiO2-(10-x)Ga2O3-xYb2O3(x=0.5,2.0,5.0)掺镱铋酸盐玻璃在1 μm近红外波段发光的温度特性。测定了9 K低温到350 K高温条件下975 nm和1003 nm主次荧光峰,它们的半峰全宽基本没有大的变化,表明铋酸盐玻璃基质对镱离子的非均匀加宽是谱线加宽的主要原因。另外,电子声子耦合对镱离子荧光光谱和荧光寿命也有一定程度的影响。对于荧光寿命的温度特性,本身具有较大荧光俘获效应的镱离子的寿命受到明显影响,其中在高温区的影响比在低温区的更强。

Abstract

The temperature dependence of near-infrared around 1 μm emission properties of Yb-doped 55Bi2O3-25B2O3-10SiO2-(10-x)Ga2O3-xYb2O3(x=0.5, 2.0, 5.0) glasses is investigated. Emission spectra, covering a major 975 nm fluorescence peak with a minor 1003 nm weaker peak, are determined within the temperature range of 9 K~350 K. The full width at half-maximum of them does not change a lot. An important cause for the width of fluorescence line is inhomogeneous broadening from this bismuth-based glass host. On the other hand, the electron-phonon coupling will have some influence on the emission spectrum and emission lifetime. For the temperature dependence of lifetime, a longer emission lifetime of Yb at higher temperature region indicates a more significant influence of radiation trapping effect.

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中图分类号:TQ171.73+5

DOI:10.3788/cjl201340.1015001

所属栏目:光谱学

责任编辑:韩峰  信息反馈

收稿日期:2013-04-16

修改稿日期:2013-05-10

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程继萌:中国科学院上海光学精密机械研究所, 上海 201800
李韦韦:中国科学院上海光学精密机械研究所, 上海 201800
赵国营:中国科学院上海光学精密机械研究所, 上海 201800
李顺光:中国科学院上海光学精密机械研究所, 上海 201800
陈伟:中国科学院上海光学精密机械研究所, 上海 201800
胡丽丽:中国科学院上海光学精密机械研究所, 上海 201800
Georges Boulon:Institute Light Matter, UMR5306 University of Lyon1-CNRS, University of Lyon, Bat. Kastler, 69622 Villeurbanne cedex, France

联系人作者:程继萌(chengjimeng@siom.ac.cn)

备注:程继萌(1985—),男,助理工程师,主要从事光学材料光谱方面的研究。

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引用该论文

Cheng Jimeng,Li Weiwei,Zhao Guoying,Li Shunguang,Chen Wei,Hu Lili,Georges Boulon. Temperature Characteristics of Near-Infrared Luminescence of Yb-Doped Bismuth-Based Glasses[J]. Chinese Journal of Lasers, 2013, 40(10): 1015001

程继萌,李韦韦,赵国营,李顺光,陈伟,胡丽丽,Georges Boulon. 掺镱铋酸盐玻璃近红外发光的温度特性[J]. 中国激光, 2013, 40(10): 1015001

被引情况

【1】昌剑,张运海,张欣,姜琛昱. 激光扫描共聚焦技术在近红外荧光成像中的应用. 激光与光电子学进展, 2014, 51(11): 111702--1

【2】李欢欢,卢伟,洪德林,党晓景,梁琨. 基于特征光谱和GRNN 的糙米发芽率快速检测方法研究. 激光与光电子学进展, 2015, 52(11): 113005--1

【3】李栋宇,黄贞,全军,谢木标,聂仲泉,黄传海,王玉晓. ZrO2∶Er3+/Yb3+/Li+纳米晶的上转换荧光特性与温度传感研究. 中国激光, 2015, 42(12): 1206004--1

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