中国激光, 2014, 41 (3): 0303005, 网络出版: 2014-02-28
Ti-6Al-4V合金激光熔覆γ-NiCrAlTi/TiC+TiWC2/CrS+Ti2CS高温自润滑耐磨复合涂层研究
Study on γ-NiCrAlTi/TiC+TiWC2/CrS+Ti2CS High-Temperature Self-Lubricating Wear Resistant Composite Coating on Ti-6Al-4V by Laser Cladding
光学制造 固体润滑 高温耐磨复合涂层 optical fabrication solid lubrication high-temperature wear resistant composite coating Ti-6Al-4V Ti-6Al-4V
摘要
为提高Ti-6Al-4V钛合金的摩擦学性能,以金属陶瓷NiCr-Cr3C2和自润滑颗粒WS2复合合金粉末为原料,采用激光熔覆技术在钛合金表面制备出了以硬质TiC和TiWC2为耐磨增强相、Ti2CS和CrS金属硫化物为自润滑相的高温自润滑耐磨复合涂层。采用 X射线衍射仪(XRD)、扫描电子显微镜(SEM)、能谱仪(EDS)分析了涂层的物相及显微组织结构;分别在室温、300 ℃和600 ℃时利用Si3N4陶瓷球对磨来测试涂层和基体的干滑动磨损性能,并分析了其磨损机理。结果表明:复合涂层的平均硬度为1005 HV0.2,约为基体(360 HV0.2)的3倍,从室温到600 ℃,由于增强相TiC、TiWC2和自润滑相CrS、Ti2CS的综合效应,复合涂层的摩擦系数和磨损率相比基体均显著降低,具有良好的高温自润滑耐磨性能。
Abstract
To enhance the tribological behaviors of Ti-6Al-4V alloy, high-temperature self-lubricating wear resistant composite coatings reinforced with hard TiC and TiWC2 carbides, self-lubricating Ti2CS and CrS sulfides are fabricated by laser cladding. The phase compositions and microstructures are investigated by X-ray diffractometer (XRD), scanning electron microscope (SEM) and energy dispersive spectrometer (EDS), respectively. Sliding wear tests of the composite coating and substrate are conducted at ambient temperature, 300 ℃ and 600 ℃, with the Si3N4 ceramic ball as the counter-body, and the corresponding wear mechanisms are discussed. Results indicate that the mean microhardness of the composite coating (1005 HV0.2) is about 2 times higher than that of substrate (360 HV0.2). From ambient temperature to 600 ℃, due to the combined effects of hard TiC and TiWC2 carbides and self-lubricating Ti2CS and CrS sulfides, both the friction coefficient and wear rate of the composite coating decrease in comparison with the substrate. The composite coating has excellent high temperature self-lubricating and wear resistant properties.
刘海青, 刘秀波, 孟祥军, 孙承峰, 王明娣, 石皋莲, 吴少华. Ti-6Al-4V合金激光熔覆γ-NiCrAlTi/TiC+TiWC2/CrS+Ti2CS高温自润滑耐磨复合涂层研究[J]. 中国激光, 2014, 41(3): 0303005. Liu Haiqing, Liu Xiubo, Meng Xiangjun, Sun Chengfeng, Wang Mingdi, Shi Gaolian, Wu Shaohua. Study on γ-NiCrAlTi/TiC+TiWC2/CrS+Ti2CS High-Temperature Self-Lubricating Wear Resistant Composite Coating on Ti-6Al-4V by Laser Cladding[J]. Chinese Journal of Lasers, 2014, 41(3): 0303005.