光子学报, 2014, 43 (3): 0316002, 网络出版: 2014-04-09
橙红色荧光粉Ca3Y2(Si3O9)2∶Sms3+的制备及发光性能的表征
Preparation and Luminescence Properties of Reddish-orange Phosphors Ca3Y2(Si3O9)2∶Sms3+
摘要
采用高温固相法合成了Ca3Y2-2x(Si3O9)2∶2xSm3+系列荧光粉,并表征了材料的发光特性.X射线衍射图谱表明:得到的样品为纯相Ca3Y2(Si3O9)2晶体;样品的激发光谱主要来源于Sm3+的特征激发;分别采用紫外、近紫外和蓝光作为激发源,样品均发射橙红光.在402 nm近紫外光激发下,Ca3Y2(Si3O9)2∶Sm3+发射光谱主要由3个峰组成,发射峰值分别位于565 nm、604 nm和651 nm,归属于Sm3+的4G5/2→6HJ/2(J=5, 7, 9)跃迁,其中发射主峰位于604 nm处.通过时间分辨光谱测得Sm3+的4G5/2能级的荧光寿命.随着Sm3+摩尔浓度的增加,样品发光强度先增强后减弱,当x=0.02时发光强度达到最大,浓度猝灭机理为电偶极-电偶极相互作用.
Abstract
A series of orange-red phosphors Ca3Y2-2x(Si3O9)2∶2xSm3+ were synthesized by conventional solid-state reaction, and their photoluminescence properties were investigated. The X-ray diffraction (XRD) pattern shows that Ca3Y2(Si3O9)2∶Sm3+ crystals are the pure phase. The excitation spectra contain the characteristic excitation of Sm3+. The emission spectra of Ca3Y2(Si3O9)2∶Sm3+ phosphors exhibit three main peaks assigned to the 4G5/2→6HJ/2(J=5,7,9) transitions of Sm3+ under 402 nm excited radiation, the dominating emission peaks at 565 nm, 604 nm, 651 nm. The decay time of 4G5/2 level in Sm3+ was measured by the time resolved spectrum. The luminescence intensity firstly increases with increasing of Sm3+ concentration, and then decreases, the emission reaches the maximum intensity at x=0.02, and the concentration quenching mechanism is the electric dipole-electric dipole interaction.
杨志平, 梁晓双, 赵引红, 侯春彩, 王灿, 董宏岩, 刘利鹏. 橙红色荧光粉Ca3Y2(Si3O9)2∶Sms3+的制备及发光性能的表征[J]. 光子学报, 2014, 43(3): 0316002. YANG Zhi-ping, LIANG Xiao-shuang, ZHAO Yin-hong, HOU Chun-cai, WANG Can, DONG Hong-yan, LIU Li-peng. Preparation and Luminescence Properties of Reddish-orange Phosphors Ca3Y2(Si3O9)2∶Sms3+[J]. ACTA PHOTONICA SINICA, 2014, 43(3): 0316002.