通过高温固相反应在空气中制备了BaMgSiO4:Eu2+/Eu3+发光材料，利用粉末X射线衍射(XRD)、红外光谱（FTIR）、扫描电镜（SEM）、荧光光谱 (PL)对合成的样品进行表征。研究表明，在393 nm激发光激发下，BaMgSiO4:Eu2+/Eu3+材料同时表现出Eu2+和Eu3+的发射光谱；改变NH4Cl质量分数可有效调整Eu2+和Eu3+的发光强度，实现从绿光到白光的有效调控。Eu3+发光强度随着NH4Cl用量增加而增大；当NH4Cl质量分数为5%时， Eu2+和Eu3+的发光强度比（I Eu2+/Eu3+）最低，可获得国际照明委员会（CIE）色坐标为（0.37,0.38）、色温（CCT）为4300 K的暖白光。BaMgSiO4:Eu2+/Eu3+表现出良好的热稳定性，在200 ℃时，其发光强度仅下降了15%。研究表明BaMgSiO4:Eu2+/Eu3+荧光粉可作为潜在的单一掺杂单一组成的白光发光二极管(LED)发光材料。

The BaMgSiO4:Eu2+/Eu3+ phosphors are prepared in air atmosphere by a conventional solid-state reaction, the properties of BaMgSiO4:Eu2+/Eu3+ phosphors are investigated through X-ray diffraction (XRD), infrared spectroscopy (FTIR), scanning electron microscope (SEM) and photoluminescence (PL). The results suggest that the emission spectra of Eu2+ and Eu3+ ions are both presented in the Eu-doped BaMgSiO4 phosphors under the excitation of 393 nm, and the emission intensity of Eu2+/Eu3+ can be changed with the NH4Cl contents to achieve tunable spectra from green light to white light. The PL intensity of Eu3+ is improved with increasing of NH4Cl contents, and the value of I Eu2+/Eu3+ is the smallest when adding 5% NH4Cl in the BaMgSiO4:Eu2+/Eu3+. The warm white light with international commission on illumination (CIE) chromaticity coordinates (0.37, 0.38) and color temperature CCT (4300 K) is obtained. BaMgSiO4:Eu2+/Eu3+ phosphor shows better thermal stability because the emission intensity measured at 200 ℃ is only decreased 15% compared with that measured at room temperature. The results show that BaMgSiO4:Eu2+/Eu3+ can be used as potential single-doped and single-composition white light emitting diode (LED) phosphors.