红外与毫米波学报, 2014, 33 (2): 139, 网络出版: 2014-05-06  

微纳BNT铁电薄膜阵列制备及性能研究

Preparation and performance of micro/nano-scale Bi3.15Nd0.85Ti3O12/Si-MCP ferroelectric thin film arrays
作者单位
1 中国科学院上海技术物理研究所 红外物理国家重点实验室,上海200083
2 齐齐哈尔大学 通信与电子工程学院,黑龙江 齐齐哈尔161006
3 华东师范大学 极化材料与器件教育部重点实验室,上海20024
摘要
采用溶胶-凝胶和旋涂抽滤方法,在硅微通道(Si-MCP)衬底的内壁上涂敷前驱物,然后分别在600 ℃, 650 ℃,700 ℃和750 ℃条件下制备Bi3.15Nd0.85Ti3O12/Si-MCP 微纳薄膜阵列,并对其结构及铁电特性进行表征.研究结果显示,退火温度越高,Si-MCP内被局域化的微纳薄膜结晶颗粒尺寸越大,同时BNT/Si-MCP微纳薄膜阵列越趋向沿c 轴取向,尤其在750 ℃ 下制备的薄膜具有表面形貌均匀和c轴取向程度高等优点,且剩余极化强度可达93.8 μC/cm2.
Abstract
The micro/nano-scale Bi3.15Nd0.85Ti3O12/Si-MCP (BNT/Si-MCP) ferroelectric thin film arrays were fabricated successfully by the sol-gel, spin-coating and pumping filtration methods. Precursors of BNT were coated on the inner wall of Si-MCP. Bi3.15Nd0.85Ti3O12 thin film supported by Si-MCP were prepared via annealing in oxygen atmosphere at 600℃, 650℃, 700℃ and 750℃, respectively. The ferroelectric properties and microstructures of BNT/Si-MCP film arrays were characterized. The results show that with the increase of annealing temperature, the size of BNT grain localized on the inner wall of Si-MCP increases, the uniformity of the surface and the degree of orientation along the c-axis increase, too. The largest remanent polarization (93.8 μC/cm2) and lowest leakage current of the micro/nano-scale BNT/Si-MCP arrays were obtained annealing at 750℃.

苗凤娟, 陶佰睿, 胡志高, 褚君浩. 微纳BNT铁电薄膜阵列制备及性能研究[J]. 红外与毫米波学报, 2014, 33(2): 139. MIAO Feng-Juan, TAO Bai-Rui, HU Zhi-Gao, CHU Jun-Hao. Preparation and performance of micro/nano-scale Bi3.15Nd0.85Ti3O12/Si-MCP ferroelectric thin film arrays[J]. Journal of Infrared and Millimeter Waves, 2014, 33(2): 139.

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