光学学报, 2016, 36 (3): 0330001, 网络出版: 2016-03-03
基于可调谐半导体激光吸收光谱的氧气浓度测量研究 下载: 541次
Measurement of Oxygen Concentration Using Tunable Diode Laser Absorption Spectroscopy
光谱学 可调谐半导体激光吸收光谱 自动增益控制 Levenberg-Marquardt非线性拟合 氧气浓度测量 spectroscopy tunable diode laser absorption spectroscopy automatic gain control Levenberg-Marquardt nonlinear fitting oxygen concentration measurement
摘要
采用可调谐半导体激光吸收光谱(TDLAS)技术,利用氧气在760 nm 波段的吸收谱线对氧气浓度进行实时在线测量。研制了基于TDLAS直接吸收技术的氧气检测系统,采用压控放大器设计了自动增益控制模块,实现了对光谱信号幅度的精确控制,解决了现场测量中信号幅度波动的问题;采用归一化洛伦兹函数实现Voigt函数的近似计算,并结合Levenberg-Marquardt非线性拟合算法实现了对光谱吸光度曲线的快速Voigt线型拟合,以适应实时在线检测需要。实验结果表明,该算法可以实现吸光度曲线的Voigt线型拟合,对固定浓度的氧气进行连续测量得到系统的最低检测限为523×10-6 m,系统的标准偏差为1.75%。检测系统稳定可靠,满足实时在线氧气浓度检测应用。
Abstract
The tunable diode laser absorption spectroscopy (TDLAS) technology and oxygen absorption lines near 760 nm are used to realize real-time on-line measurement of oxygen concentration. A detection system based on TDLAS direct absorption technique is designed. In order to solve signal amplitude fluctuation for on- site measurement, an automatic gain control module is designed using voltage controlled amplifier to achieve precise control of the spectrum signal amplitude; generalized Lorentz function is adopted to realize the approximate calculation of Voigt function combining Levenberg-Marquardt nonlinear fitting method to realize fast Voigt profile fitting of the absorbance spectrum curve, to meet the requirement of real-time on-line detection. Experimental results show that the algorithm can achieve Voigt profile fitting of absorbance curve. A fixed concentration of oxygen is continuously measured. Minimum detection limit of the system is 523 × 10-6 m, and standard deviation is 1.75%. Detection system is reliable and meets the real-time on-line oxygen concentration detection applications.
高彦伟, 张玉钧, 陈东, 何莹, 尤坤, 陈晨, 刘文清. 基于可调谐半导体激光吸收光谱的氧气浓度测量研究[J]. 光学学报, 2016, 36(3): 0330001. Gao Yanwei, Zhang Yujun, Chen Dong, He Ying, You Kun, Chen Chen, Liu Wenqing. Measurement of Oxygen Concentration Using Tunable Diode Laser Absorption Spectroscopy[J]. Acta Optica Sinica, 2016, 36(3): 0330001.