合成了新型尾式5-(2-(α-咪唑基间甲基苯甲酰胺基)苯基)-10，15，20-三苯基卟啉(H2TPP-BzIm)及其Fe、Co、Zn配合物，并用核磁、质谱、红外光谱、紫外-可见光谱等对其化合物进行了表征，通过紫外吸收、荧光分析、循环伏安法研究了化合物的光电性质。结果表明，与四苯基卟啉(H2TPP)相比，该尾式卟啉及其配合物的紫外和荧光光谱均出现较明显红移。Fe和Co卟啉的循环伏安曲线表明不仅发生了卟啉环上的氧化还原反应，还发生了金属离子的氧化还原反应。

A new tailed-porphyrin H2TPP-BzIm and different transition metalloporphyrins (Fe, Co, Zn) were synthesized and characterized by 1H NMR, MS, IR, UV-Vis. The spectral and electrochemical properties were studied by UV-Vis spectrum, fluorescence spectrum and cyclic voltammetry method. Compared with tetraphenyporphyrin(H2TPP), the absorption and emission peaks of the tailed porphyrin have obvious red-shifts. The CV curves of Fe, Co metalloporphyrins indicate that Fe and Co undergo the changing of oxidation state in addition to the redox on the porphyrin ring.