红外技术, 2016, 38 (6): 524, 网络出版: 2016-07-26
基于红外谱图的低发射率涂层用基体树脂的判定方法
A Judgement Method of Matrix Resin Based on Infrared Spectra of Low Emissivity Coatings
傅里叶红外光谱 树脂 吸光度系数 红外发射率 Kubelka-Munk理论 infrared spectra resin absorption coefficient infrared emissivity Kubelka-Munk theory
摘要
提出一种以吸光度系数为指标来筛选低发射率涂层用基体树脂的判定方法。从分析丙烯酸树脂、环氧树脂和聚氨酯树脂 3种树脂的傅里叶红外光谱入手, 根据 Lambert-Beer定律对 3种树脂的红外光谱进行定量分析, 得出树脂在 8~14 .m波段的吸光度系数曲线, 并且积分求得 3种树脂在该波段的平均吸光度系数。通过比较分析, 丙烯酸树脂的吸光度系数最小, 为 0.0293 .m-1, 制得的清漆涂层的红外发射率最低, 为 0.90, 适合作为低发射率涂层用基体树脂;最后, 建立红外辐射一维传输模型, 推导涂层红外发射率理论公式, 理论证明了以吸光度系数为判定指标的合理性。
Abstract
A method screening the matrix resin of low emissivity coatings was promoted, whose index was the absorption coefficient. The infrared spectra of three kinds of resins, including acrylic resin, polyurethane resin and epoxy resin, were analyzed. According to the Lambert Beer's law, quantitative analysis was carried out on the infrared spectra of three kinds of resins, and the absorption coefficient curve at 8-14 .m and the average absorption coefficient were got. Through comparative analysis, the absorption coefficient of acrylic resin is the smallest, which is 0.0293 .m-1, and its infrared emissivity is the lowest, which is 0.90. For these reasons, acrylic resin is proper to be the matrix resin of a low emissivity coating. Finally, the infrared radiation transmission model of one-dimension was established, and the theoretical formula of infrared emissivity was derived, therefore, the reasonability of the absorption coefficient was proved by this theory.
叶圣天, 刘朝辉, 成声月, 王飞, 贾艺凡, 李振强. 基于红外谱图的低发射率涂层用基体树脂的判定方法[J]. 红外技术, 2016, 38(6): 524. YE Shengtian, LIU Zhaohui, CEHNG Shengyue, WANG Fei, JIA Yifan, LI Zhenqiang. A Judgement Method of Matrix Resin Based on Infrared Spectra of Low Emissivity Coatings[J]. Infrared Technology, 2016, 38(6): 524.