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Yb3+掺杂铋酸盐玻璃的发光特性

Luminescence Properties of Yb3+-Doped Bismuthate Glass

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摘要

研究了Yb3+掺杂铋酸盐玻璃的发光特性参数, 讨论了Yb2+、Bi3+等缺陷淬灭中心与Yb3+之间的能量转移。对于已优化的基质组成, 在荧光寿命没有大幅下降的前提下, 玻璃中Yb3+近红外波段的发射截面明显增大, 吸收截面减小, 激光增益能力和饱和抽运强度均得到提高。采用有效的除羟基工艺, 玻璃中不会产生比磷酸盐玻璃中更为严重的Yb3+发光淬灭效应, 但铋酸盐玻璃中还可能存在Yb2+、Bi3+等价态不稳定的缺陷淬灭中心。

Abstract

The luminescence property parameters of the Yb3+-doped bismuthate glass are investigated, and the energy transfer from those defect quenching centers such as Yb2+ and Bi3+ to Yb3+ is also discussed. Based on the optimized matrix composition and without the sharp decline of the fluorescence lifetime, the near-infrared emission cross-section of Yb3+ in glass is obviously increased, the absorption cross-section is reduced, and the capability of laser gain and the saturation pump intensity are both enhanced. By the efficient dehydroxyl process, the luminescence quenching effect of Yb3+ in the bismuthate glass may not be stronger than that in the phosphate glass. However, there exist probably some defect quenching centers such as Bi3+ and Yb2+ with unstable valence states in the bismuthate glass.

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中图分类号:TN244;TQ135.3+2

DOI:10.3788/cjl201744.0903001

所属栏目:材料与薄膜

基金项目:国家自然科学基金(61475171)

收稿日期:2017-04-25

修改稿日期:2017-05-18

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汪韬:中国科学院上海光学精密机械研究所高功率激光单元技术研发中心, 上海 201800中国科学院大学, 北京 100049
范慧艳:中国科学院上海光学精密机械研究所高功率激光单元技术研发中心, 上海 201800
赵国营:中国科学院上海光学精密机械研究所高功率激光单元技术研发中心, 上海 201800
程继萌:中国科学院上海光学精密机械研究所高功率激光单元技术研发中心, 上海 201800
陈伟:中国科学院上海光学精密机械研究所高功率激光单元技术研发中心, 上海 201800
胡丽丽:中国科学院上海光学精密机械研究所高功率激光单元技术研发中心, 上海 201800
Guzik Malgorzata:弗罗茨瓦夫大学化学学院, 弗罗茨瓦夫 50-383, 波兰
Boulon Georges:里昂大学光物质研究所, 维勒班 69622, 法国

联系人作者:汪韬(semarhai@qq.com)

备注:汪韬(1990-), 男, 硕士研究生, 主要从事激光玻璃材料性能方面的研究。

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引用该论文

Wang Tao,Fan Huiyan,Zhao Guoying,Cheng Jimeng,Chen Wei,Hu Lili,Guzik Malgorzata,Boulon Georges. Luminescence Properties of Yb3+-Doped Bismuthate Glass[J]. Chinese Journal of Lasers, 2017, 44(9): 0903001

汪韬,范慧艳,赵国营,程继萌,陈伟,胡丽丽,Guzik Malgorzata,Boulon Georges. Yb3+掺杂铋酸盐玻璃的发光特性[J]. 中国激光, 2017, 44(9): 0903001

被引情况

【1】赵海琴,王林香,庹娟,叶颖,李国娇. Li+/Bi3+共掺杂Lu2O3∶Ho3+荧光粉的制备及其发光特性. 激光与光电子学进展, 2018, 55(8): 81602--1

【2】金文田,赵国营,徐玲芝,邱娟,侯京山,刘玉峰,房永征,廖梅松,胡丽丽. Tm3+/Dy3+共掺铋酸盐玻璃的1.47 μm宽带发光. 中国激光, 2018, 45(9): 903002--1

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