光子学报, 2018, 47 (3): 0316003, 网络出版: 2018-02-01
TiO2/MoO3复合薄膜的制备及其电致变色性能研究
Preparation and Electrochromic Properties of TiO2/MoO3 Composite Film
薄膜 电致变色 电化学测试 光透射率 Thin films Electrochromic Electrochemical measurement Optical transmittance TiO2 TiO2 MoO3 MoO3
摘要
在导电玻璃上水热生长TiO2纳米线, 随后利用电沉积技术涂覆MoO3薄膜, 制备出TiO2/MoO3复合薄膜.通过X射线衍射、扫描电子显微镜表征证实了TiO2/MoO3复合薄膜的形成.利用电化学测试方法, 在LiClO4/PC溶液中对Li+的注入/抽出进行了研究, 采用紫外可见分光光度计对薄膜着色、退色状态的光透过率进行测试.得到了切换时间、循环可逆性、光调制和着色效率等参数.对其电致变色性能进行分析, 分析表明, 与单一TiO2和MoO3薄膜的电致变色性能相比, 复合薄膜的电致变色性能有明显增强.同时研究了不同厚度MoO3薄膜对复合薄膜变色性能的影响, 研究表明沉积6个循环MoO3薄膜的TiO2/MoO3复合薄膜具有最佳的电致变色性能.
Abstract
TiO2 nanowire arrays were generated on FTO glass by hydrothermal method, and then the TiO2/MoO3 composite film was prepared through electrodepositing MoO3 coating onto TiO2 nanowire arrays. The formation of TiO2/MoO3 composite films were confirmed by X-ray diffraction and scanning electron microscope. Li+ insertion/extraction in LiClO4/PC solution had been studied by electrochemical measurement technologies, and the optical transmittance of the samples in the colored and bleached states were used by UV-Vis NIR spectrophotometer. The parameters of switching time, reversibility, optical modulation and coloration efficiency were obtained. Then, the electrochromic properties were analyzed. The analysis showed that the electrochromic properties of the TiO2/MoO3 composite films were obviously enhanced for comparing with the TiO2 nanowire and MoO3 films. The effects of different thickness MoO3 coating on the discoloration properties of the composite films were studied. The results showed that TiO2/MoO3 composite films with 6 cycles of MoO3 thin films had the best electrochromic performance.
亢嘉琪, 杨继凯, 杨馥瑜, 陈张笑雄, 王国政, 端木庆铎. TiO2/MoO3复合薄膜的制备及其电致变色性能研究[J]. 光子学报, 2018, 47(3): 0316003. KANG Jia-qi, YANG Ji-kai, YANG Fu-yu, CHEN Zhang-xiao-xiong, WANG Guo-zheng, DUAN-MU Qing-duo. Preparation and Electrochromic Properties of TiO2/MoO3 Composite Film[J]. ACTA PHOTONICA SINICA, 2018, 47(3): 0316003.