红外与激光工程, 2018, 47 (6): 0621003, 网络出版: 2018-09-08   

色散效应对钝化硅太阳电池减反射膜系设计的影响

Dispersion effect on optimized design of anti-reflection coatings for passivated silicon solar cells dispersion
作者单位
1 西安工程大学 理学院, 陕西 西安 710048
2 内蒙古工业大学 理学院, 内蒙古 呼和浩特 010051
摘要
在考虑折射率色散效应基础上, 以加权平均反射率作为评价函数, 通过智能优化算法对空间硅太阳电池减反射膜进行优化设计, 得到了最佳的膜厚参数, 并与不考虑色散下设计的减反射膜进行了比较。对MgF2/TiO2, SiO2/ TiO2双层减反射膜, 与不考虑色散情形相比, 考虑色散下优化后的最小加权平均反射率分别减小了36.6%和37.6%; 对具有厚度为15 nm的SiO2钝化层的硅太阳电池的MgF2/TiO2, SiO2/ TiO2减反射膜重新优化设计, 与不考虑色散情形相比, 考虑色散下优化后的最小加权平均反射率分别减小了43.9%和33.7%; 对具有不同厚度钝化层的空间硅太阳电池, 在考虑色散下进行了减反射膜的优化设计。结果发现, 随着钝化层厚度的增加, 所得减反射膜的最小加权平均反射率也随之增大, 减反射效果越来越弱。最后, 在考虑与未考虑色散情形下, 将钝化层膜厚也作为反演参量后重新设计。结果表明: 在色散情形下所设计的减反射膜更佳, 对于MgF2/TiO2/SiO2(钝化层)膜系, 最佳膜厚参量为d1(MgF2)=97.6 nm, d2(TiO2)=40.2 nm, d3(SiO2)=4.9 nm; 对于SiO2/TiO2/ SiO2(钝化层), 最佳膜厚参量为d1(SiO2)=85.1 nm, d2(TiO2)=43.4 nm, d3(SiO2)=1.8 nm。
Abstract
Based on the refractive index dispersion effect, the weighted average reflectivity was used as evaluation function, and the best film thickness parameters of the anti-reflection coatings for the space silicon solar cell was obtained by the intelligent optimization algorithm. The optimization results were compared with that of the anti-reflection coatings designed without considering the dispersion. It displayed that after optimizing, the minimal weighted average reflectivity of the MgF2/TiO2 and SiO2/ TiO2 anti-reflection coatings were reduced by 36.6% and 37.6% under considering the dispersion effect than that without considering dispersion effect. And then the MgF2/TiO2 and SiO2/TiO2 anti-reflection coatings were deposited on the silicon solar cells with a thickness of 15 nm SiO2 passivation layer and optimized again. Comparing without considering dispersion effect, the minimal weighted average reflectivity in the case of dispersion was reduced by 43.9% and 33.7% for the MgF2/TiO2 and SiO2/TiO2 coatings with passivation layer, respectively. The optimal design of the anti-reflection coatings were carried out for the space silicon solar cells with different thickness passivation layer. It was found that the minimum weighted average reflectivity of the anti-reflection coatings increased with the increase of the thickness of the passivation layer, meaning that the anti-reflection effect got weaker and weaker. Finally, the anti-reflection coatings were redesigned when the thickness of the passivation layer was also considered as an inversion parameter considering the refractive-index dispersion effect or not. The results show that the anti-reflection film is more optimization by considering the dispersion. For the MgF2/TiO2/SiO2(passivation layer) film system, the optimal film thickness parameters are d1(MgF2)=97.6 nm, d2(TiO2)=40.2 nm, d3(SiO2)=4.9 nm. For the SiO2/TiO2/ SiO2(passivation layer) film system, the optimal film thickness parameters are d1(SiO2)=85.1 nm, d2(TiO2)=43.4 nm, d3(SiO2)=1.8 nm.

王安祥, 张晓军, 李继军. 色散效应对钝化硅太阳电池减反射膜系设计的影响[J]. 红外与激光工程, 2018, 47(6): 0621003. Wang Anxiang, Zhang Xiaojun, Li Jijun. Dispersion effect on optimized design of anti-reflection coatings for passivated silicon solar cells dispersion[J]. Infrared and Laser Engineering, 2018, 47(6): 0621003.

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