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Oxygen-containing-defect-induced synergistic nonlinear optical enhancement of graphene/CdS nanohybrids under single pulse laser irradiation

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Abstract

Oxygen-containing defects are very important for altering the nonlinear optical (NLO) properties of graphene. To investigate the correlation between oxygen-containing defects and the synergistic NLO response in graphene-based nanocomposites, we attached CdS nanocrystals on the surface of graphene (G) and prepared G/CdS nanohybrids (NHs) consisting of various oxygen-containing functional groups via a chemical method. The NLO absorption and refraction of G/CdS NHs under single pulse laser irradiation are enhanced by 10.8 times with the concentration decrease of surface oxygen-containing groups, which might be attributed to the local field effects and synergetic effects stemming from charge transfer between the two components. However, the optical nonlinearity is decreased with further concentration decrease, which might arise from sp2 fragment interconnection and surface defects in the NHs. The NLO absorption transformation from two-photon absorption to saturable absorption with oxygen decrease is observed, and intensity-related NLO absorption and refraction in NHs are also discussed. Meanwhile, the G/CdS NHs exhibit superior NLO properties, implying potential applications of NH material in NLO devices.

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DOI:10.1364/prj.6.001158

基金项目:National Natural Science Foundation of China (NSFC)10.13039/501100001809 (61404045, U1404624, 61875053); Natural Science Foundation of Henan Province10.13039/501100006407 (144300510018); Scientific Research Funds of Henan University (CX0000A40680).

收稿日期:2018-06-21

录用日期:2018-09-03

网络出版日期:2018-10-17

作者单位    点击查看

Baohua Zhu:Institute of Micro/Nano Photonic Materials and Applications, School of Physics and Electronics, Henan University, Kaifeng 475004, China
Fangfang Wang:Key Laboratory of Infrared Imaging Materials and Detectors, Shanghai Institute of Technical Physics, Chinese Academy of Sciences, Shanghai 200083, China
Guixia Wang:Institute of Micro/Nano Photonic Materials and Applications, School of Physics and Electronics, Henan University, Kaifeng 475004, China
Yuzong Gu:Institute of Micro/Nano Photonic Materials and Applications, School of Physics and Electronics, Henan University, Kaifeng 475004, Chinae-mail: 10110105@vip.henu.edu.cn

联系人作者:Baohua Zhu(bhzhu@henu.edu.cn)

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引用该论文

Baohua Zhu, Fangfang Wang, Guixia Wang, and Yuzong Gu, "Oxygen-containing-defect-induced synergistic nonlinear optical enhancement of graphene/CdS nanohybrids under single pulse laser irradiation," Photonics Research 6(12), 1158-1169 (2018)

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