人工晶体学报, 2020, 49 (10): 1911, 网络出版: 2021-01-09  

纳米Y2O3悬浮液流变性能及注浆成型研究

Rheological Behavior and Slip Casting of Nano Y2O3 Aqueous Suspension
作者单位
辽宁石油化工大学机械工程学院,抚顺 113001
摘要
以比表面积为18.1 m2/g的纳米粉体Y2O3为原料,柠檬酸铵(TAC)作为分散剂制备Y2O3悬浮液,研究TAC含量、pH值、球磨时间及固相含量对Y2O3悬浮液流变性能的影响。结果表明:加入2.2%(质量分数)的TAC,调节悬浮液的pH值为9.4~11.5,球磨8 h可以获得分散稳定的Y2O3悬浮液;悬浮液的粘度随固相含量的增加而增大,对不同固相含量的悬浮液进行注浆成型,发现固相含量为33%(体积分数)的悬浮液致密度最高。与传统的模压成型工艺相比,注浆成型得到的坯体中粉体颗粒分散均一。
Abstract
Aqueous Y2O3 suspension was prepared by Y2O3 nano powders with a specific surface area of 18.1 m2/g as raw material and ammonium citrate (TAC) as dispersant, respectively. The influence of concentration of TAC, pH value, ball-milling time and solid loading on the rheological behavior of Y2O3 suspension was investigated. The results indicate that the stable and well-dispersed suspension with 2.2%(mass fraction) TAC and pH value in the range of 9.4 to 11.5 was achieved after 8 h ball-milling. The viscosity of the suspensions increases with increasing solid loading, and the green body of slip casting from 33%(volume fraction) suspension has the highest density. Compared with the traditional die pressing, more homogeneous powder particles in green bodies by slip casting are obtained.

常玉坤, 王涛, 何娇, 张雪, 连景宝. 纳米Y2O3悬浮液流变性能及注浆成型研究[J]. 人工晶体学报, 2020, 49(10): 1911. CHANG Yukun, WANG Tao, HE Jiao, ZHANG Xue, LIAN Jingbao. Rheological Behavior and Slip Casting of Nano Y2O3 Aqueous Suspension[J]. Journal of Synthetic Crystals, 2020, 49(10): 1911.

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