Powerful lasers interacting with solid targets can generate intense electromagnetic pulses (EMPs). In this study, EMPs produced by a pulsed laser (1 ps, 100 J) shooting at CH targets doped with different titanium (Ti) contents at the XG-III laser facility are measured and analyzed. The results demonstrate that the intensity of EMPs first increases with Ti doping content from 1% to 7% and then decreases. The electron spectra show that EMP emission is closely related to the hot electrons ejected from the target surface, which is confirmed by an analysis based on the target–holder–ground equivalent antenna model. The conclusions of this study provide a new approach to achieve tunable EMP radiation by adjusting the metal content of solid targets, and will also help in understanding the mechanism of EMP generation and ejection of hot electrons during laser coupling with targets.