一种LED用红色荧光粉BaZn2(BO3)2∶Eu3+的合成与发光性能研究
吴程潇, 邓德刚, 阮枫萍, 余华, 徐时清. 一种LED用红色荧光粉BaZn2(BO3)2∶Eu3+的合成与发光性能研究[J]. 发光学报, 2018, 39(4): 457.
WU Cheng-xiao, DENG De-gang, RUAN Feng-ping, YU Hua, XU Shi-qing. Synthesis and Luminescence Properties of Red Phosphor BaZn2(BO3)2∶Eu3+ for Light-emitting Diode[J]. Chinese Journal of Luminescence, 2018, 39(4): 457.
[1] YAO G Q, DUAN J F, REN M, et al.. Preparation and luminescence of blue light conversion material YAG∶Ce ［J］. J. Lumin., 2001, 22:22-26.
[2] XU Y, CHEN L H, LI Y Z. Phosphor-conversion white light using InGaN ultraviolet laser diode ［J］. Appl. Phys. Lett., 2008, 92:021129.
[3] LIN C C, LIU R S. Advances in phosphors for light-emitting diodes ［J］. Phys. Chem. Lett., 2011, 2:1268.
[4] YAN B, LIN L, WU J, et al.. Photoluminescence of rare earth phosphors Na0.5Gd0.5WO4∶RE3+ and Na0.5Gd0.5(Mo0.75-W0.25)O4∶RE3+ (RE=Eu, Sm, Dy) ［J］. J. Fluoresc., 2011, 21:203-211.
[5] ZENG X Q, SEOUNG-JAE I M, JANG S H, et al.. Luminescent properties of (Y, Gd)BO3∶Bi3+, RE3+ (RE=Eu, Tb) phosphor under VUV/UV excitation ［J］. J. Lumin., 2006, 121(1):126.
[6] TIAN L H, KIM S J, PARK H L, et al.. Variation of the photoluminescence and vacuum ultraviolet excitation characteristics of BaZr(BO3)2∶Eu3+ by the incorporation of Al3+, La3+, or Y3+ into the lattice ［J］. Mater. Res. Bull., 2006, 41(1):29-37.
[7] SUN L D, QIAN C, LIAO C S, et al.. Luminescence phosphors of Li+ doped nanosized Y2O3∶Eu3+ ［J］. Solid State Commun., 2001, 119(6):393-396.
[8] WANG Z L, LIANG H B, GONG M L, et al.. Luminescence investigation of Eu3+ activated double molybdates red phosphors with scheelite structure ［J］. J. Alloys Compd., 2007, 432:308-312.
[9] FENG G, JIANG W H, CHEN Y B, et al.. A novel red phosphor NaLa4(SiO4)3F∶Eu3+ ［J］. Mater. Lett., 2011, 65(1):110-112.
[10] DENG D G, YU H, HUA Y J, et al.. Ca4(PO4)2O∶Eu2+ red-emitting phosphor for solid-state lighting: structure, luminescent properties and white light emitting diode application ［J］. J. Mater. Chem. C, 2013, 1:3194-3199.
[11] CHEN C, WU B, JIANG A, et al.. A new-type ultraviolet SHG crystal—β-BaB2O4［J］. China Ser. B, 1985, 28:235-243.
[12] SMITH R W, KESZLER D A. The noncentrosymmetric orthoborate BaZn2(BO3)2［J］. Solid State Chem., 1992, 100:325-330.
[13] CHEN F, YUAN X, ZHANG F, et al.. Photoluminescence properties of Sr3(PO4)2∶Eu2+, Dy3+ double-emitting blue phosphor for white LEDs ［J］. Opt. Mater., 2014, 37:65-69.
[14] DORENBOS P. Energy of the first 4f7→4f65d transition of Eu2+ in inorganic compounds ［J］. J. Lumin., 2003, 104:239-260.
[15] XIE R J, HIROSAKI N, MITOMO M, at al.. Optical properties of Eu2+ in-SiAlON ［J］. Phys. Chem. B, 2004, 108:12027.
[16] HARANATH D, SHANKER V, CHANDER H, et al.. Tuning of emission colours in strontium aluminate long persisting phosphor ［J］. J. Appl. Phys., 2003, 36:2244-2248.
[17] JIE L, LIAN H Z, SHI C S. Improved optical photoluminescence by charge compensation in the phosphor system CaMoO4∶Eu3+ ［J］. Opt. Mater., 2007, 29(12):1591-1594.
[18] CHEN F, YUAN X, ZHANG F, et al.. Photoluminescence properties of Sr3(PO4)2∶Eu2+, Dy3+ double-emitting blue phosphor for white LEDs ［J］. Opt. Mater., 2014, 37:65-69.
[19] WANG Z, LIANG H, GONG M, et al.. Luminescence investigation of Eu3+ activated double molybdates red phosphors with scheelite structure ［J］. J. Alloys Compd., 2007, 432(1-2):308-312.
[20] CHEN X Y, LIU G K. The standard and anomalous crystal-field spectra of Eu3+ ［J］. Solid State Chem., 2005,178:419-428.
[21] GUO N, HUANG Y J, YOU H P, et al.. Ca9Lu(PO4)7∶Eu3+, Mn2+: a potential single-phased white-light-emitting phosphor suitable for white-light-emitting diodes ［J］. Inorg. Chem., 2010, 49(23):10907-10913
[22] BLASSE G. Energy transfer in oxidic phosphors ［J］. Philips Res. Rep., 1969, 24:131-144.
[23] YU H, DENG D G, LI Y Q, et al.. Luminescent properties of red-emitting LiSr4B3O(9-3x/2)Nx∶Eu2+ phosphor for white-LEDs ［J］. Opt. Commun., 2013, 289:103-108.
[24] LIU H, ZHANG Y, LIA L, et al.. Synthesis, broad-band absorption and luminescence properties of blue-emitting phosphor Sr8La2(PO4)6O2∶Eu2+ for n-UV white-light-emitting diodes ［J］. Ceram. Int., 2014, 40:13709-13713.
[25] LI K, GENG D, SHANG M, et al.. Color-tunable luminescence and energy transfer properties of Ca9Mg(PO4)6F2∶Eu2+, Mn2+ phosphors for UV-LEDs ［J］. J. Phys. Chem. C, 2014, 118:11026-11034.
[26] WANG Z L, LIN C K, LIU X M, et al.. Tunable photoluminescent and cathodoluminescent properties of ZnO and ZnO∶Zn phosphors ［J］. J. Lin. Phys. Chem. B, 2006, 110:9469-9476.
[27] LI H, ZHAO R, JIA Y, et al.. Sr1.7Zn0.3CeO4∶Eu3+ novel red-emitting phosphors: synthesis and photoluminescence properties ［J］. ACS Appl. Mater. Interf., 2014, 6:3163-3169.
[28] SOHN K S, CHOI Y Y, PARK H D. Photoluminescence behavior of Tb3+-activated YBO3 phosphors ［J］. J. Electrochem. Soc., 2000, 147:1988-1992.
[29] HUANG C H, KUO T W, CHEN T M. Novel red-emitting phosphor Ca9Y(PO4)7∶Ce3+, Mn2+ with energy transfer for fluorescent lamp application ［J］. ACS Appl. Mater. Interf., 2010, 2:1395-1399.
[30] LV W, JIA Y, ZHAO Q, et al.. Synthesis. structure. and luminescence properties of K2Ba7Si16O40∶Eu2+ for white light emitting diodes ［J］. J. Phys. Chem. C, 2014, 118:4649-4655.
[31] YU H, DENG D G, XU S Q, et al.. Luminescent properties of novel Ca2.89Mg0.11(PO4)2∶Eu2+ single-phase white light-emitting phosphor for white LEDs ［J］. Ceram. Int., 2015, 41:3800-3805.
[32] DEXTER D, SCHULMAN J H. Theory of concentration quenching in inorganic phosphors ［J］. J. Chem. Phys., 1954, 22:1063-1070.
吴程潇, 邓德刚, 阮枫萍, 余华, 徐时清. 一种LED用红色荧光粉BaZn2(BO3)2∶Eu3+的合成与发光性能研究[J]. 发光学报, 2018, 39(4): 457. WU Cheng-xiao, DENG De-gang, RUAN Feng-ping, YU Hua, XU Shi-qing. Synthesis and Luminescence Properties of Red Phosphor BaZn2(BO3)2∶Eu3+ for Light-emitting Diode[J]. Chinese Journal of Luminescence, 2018, 39(4): 457.
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