CaxSi合金前驱物常压氮化制备Ca1-xAlSiN3∶xEu2+红色荧光粉及发光性能研究
刘文全, 史瑞新, 段如霞, 呼格吉勒, 武文杰, 朝克夫, 包富泉, 李琪, 辛易, 特古斯. CaxSi合金前驱物常压氮化制备Ca1-xAlSiN3∶xEu2+红色荧光粉及发光性能研究[J]. 发光学报, 2017, 38(10): 1295.
LIU Wen-quan, SHI Rui-xin, DUAN Ru-xia, Hugejile, WU Wen-jie, CHAO Ke-fu, BAO Fu-quan, LI Qi, XIN Yi, O Tegus. Preparation and Luminescence Properties of Ca1-xAlSiN3∶xEu2+ Red Phosphors by Atmospheric Nitriding Method with CaxSi Alloy Precursors[J]. Chinese Journal of Luminescence, 2017, 38(10): 1295.
[1] JI H O, YANG S J, DO Y R. Healthy, natural, efficient and tunable lighting: four-package white LEDs for optimizing the circadian effect, color quality and vision performanc [J]. Light: Sci. Appl., 2014, 3(2):e141.
[2] WANG L, XIE R J, LI Y Q, et al.. Ca1-xLixAl1-xSi1+xN3∶Eu2+ solid solutions as broadband, color-tunable and thermally robust red phosphors for superior color rendition white light-emitting diodes [J]. Light: Sci. Appl., 2016, 5(1):e16155.
[3] KIM H S, MACHIDA K, HORIKAWA T, et al.. Luminescence properties of CaAlSiN3∶Eu2+ phosphor prepared by direct-nitriding method using fine metal hydride powders [J]. J. Alloys Compd., 2015, 633:97-103.
[4] LI S X, XIA P, LIU X J, et al.. Photoluminescence of CaAlSiN3∶Eu2+-based fine red-emitting phosphors synthesized by carbothermal reduction and nitridation method [J]. Opt. Mater., 2014, 38:242-247.
[5] LI J W, WATANABE T, SAKAMOTO N, et al.. Synthesis of a multinary nitride, Eu-doped CaAlSiN3, from alloy at low temperatures [J]. Chem. Mater., 2008, 20:10-15.
[6] TENG X M, LIU Y H, LIU Y Z, et al.. Preparation and luminescence properties of the red-emitting phosphor (Sr1-x-Cax)2Si5N8∶Eu2+ with different Sr/Ca ratios [J]. J. Rare Earths, 2009, 27(1):58-61.
[7] LI J F, ZHANG H R, WANG P, et al.. Luminescence properties of high-quality Ca2Si5N8∶Eu2+ phosphor: CaH2-raw material [J]. ECS J. Solid State Sci. Technol., 2013, 2(9):R165-R168.
[8] WANG C, XIN S Y, WANG X C, et al.. Double substitution induced tunable photoluminescence in the Sr2Si5N8∶Eu phosphor lattice [J]. New J. Chem., 2015, 39(9):6958-6964.
[9] 王灵利, 倪海勇, 张秋红. LED用绿色荧光粉BaSi2N2O2∶Eu2+的发光和封装性能 [J]. 发光学报, 2012, 33(5):465-469.
[10] SONG Y H, LEE M J, SONG Y L, et al.. Preparation and luminescence characteristics of single-phase rod-like BaSi2O2N2∶Eu2+ phosphor with new synthetic route for white light generation [J]. Mater. Lett., 2014, 129:178-181.
[11] SEIBALD M, ROSENTHAL T, OECKLER O, et al.. Highly efficient pc-LED phosphors Sr1-xBaxSi2O2N2∶Eu2+ (0 [12] 刘文全, 朝克夫, 武文杰, 等. CaAlSiN3∶Eu2+红色荧光粉的常压氮化制备及发光性能 [J]. 物理学报, 2016, 65(20):207801. LIU W Q, CHAO K F, WU W J, et al.. CaAlSiN3∶Eu2+ red phosphors synthesized by atmospheric nitrogen and their luminescence properties [J]. Acta Phys. Sinica, 2016, 65(20):207801. (in Chinese) [13] SUEHIRO T, HIROSAKI N, XIE R J, et al.. Blue-emitting LaSi3N5∶Ce3+ fine powder phosphor for UV-converting white light-emitting diodes [J]. Appl. Surf. Sci., 2009, 95(5):051903. [14] SHIOI K, MICHIUE Y, HIROSAKI N, et al.. Synthesis and photoluminescence of a novel Sr-SiAlON∶Eu2+ blue-green phosphor (Sr14Si68-sAl6+sOsN106-s∶Eu2+ (s approximate to 7)) [J]. J. Alloys Compd., 2011, 509(2):332-337. [15] ZEUNER M, SCHMIDT P J, SCHNICK W. One-pot synthesis of single-source precursors for nanocrystalline LED phosphors M2Si5N8∶Eu2+ (M =Sr, Ba) [J]. Chem. Mater., 2009, 21:2467-2473. [16] CHIANG C H, LIU T H, LIN H Y, et al.. Effects of flux additives on the characteristics of Y2.95Al5O12∶0.05Ce3+ phosphor: particle growth mechanism and luminescence [J]. J. Appl. Phys., 2013, 114(24):243517. [17] HU W W, CAI C, ZHU Q Q, et al.. Preparation of high performance CaAlSiN3∶Eu2+ phosphors with the aid of BaF2 flux [J]. J. Alloys Compd., 2014, 613:226-231. [18] ZHANG L, LU Z, HAN P D, et al.. The evolution and role of NH4Cl flux used to synthesize Sr2SiO4∶Dy3+ phosphor by solid-state reaction method [J]. J. Am. Ceram. Soc., 2012, 95(12):3871-3877. [19] HAN B, WANG Y F, LIU Q, et al.. Role of fluxes in the synthesis and luminescence properties of Ba3Si6O12N2∶Eu2+ oxynitride phosphors by microwave sintering [J]. J. Inorg. Mater., 2016, 31(6):652-657. [20] LI G H, CHEN J J, MAO Z Y, et al.. Atmospheric pressure preparation of red-emitting CaAlSiN3∶Eu2+ phosphors with variable fluxes and their photoluminescence properties [J]. Ceram. Int., 2016, 42(1):1756-1761. [21] ZHANG Y J, ZHAO J, WANG D J, et al.. Effect of NH4Cl flux on structural and luminescent properties of CaS∶Eu2+ phosphors [J]. Adv. Mater. Res., 2014, 989-994:755-758. [22] 姜永章, 夏海平, 张加忠, 等. 单晶体α-NaYF4∶Dy3+的制备及光谱特性 [J]. 光子学报, 2015, 44(8):0816001.
刘文全, 史瑞新, 段如霞, 呼格吉勒, 武文杰, 朝克夫, 包富泉, 李琪, 辛易, 特古斯. CaxSi合金前驱物常压氮化制备Ca1-xAlSiN3∶xEu2+红色荧光粉及发光性能研究[J]. 发光学报, 2017, 38(10): 1295. LIU Wen-quan, SHI Rui-xin, DUAN Ru-xia, Hugejile, WU Wen-jie, CHAO Ke-fu, BAO Fu-quan, LI Qi, XIN Yi, O Tegus. Preparation and Luminescence Properties of Ca1-xAlSiN3∶xEu2+ Red Phosphors by Atmospheric Nitriding Method with CaxSi Alloy Precursors[J]. Chinese Journal of Luminescence, 2017, 38(10): 1295.