原子与分子物理学报, 2008, 25 (2): 321, 网络出版: 2008-08-17
类碳体系基态能量的精细结构
Fine-structure of the ground state of carbon-like atoms
摘要
以多电子原子精细结构哈密顿的球张量形式和不可约张量理论为基础,建立了计算多电子原子精细结构(包括自旋-轨道相互作用、自旋-其它轨道相互作用和自旋-自旋相互作用)能量的一般性解析理论形式,应用所建立的理论对类碳体系(Z=6~8)基态的精细结构能量进行了具体计算,计算结果与实验数据符合得较好.
Abstract
Based on the tensor expression of the fine-structure Hamiltonian for many-electron atoms, and with the help of irreducible tensor theory, a general analytical theory of calculating the fine structure energy (including spin-orbit interaction, spin-other-orbit interaction and the spin-spin interaction) of many-electron atoms has been established explicitly. The fine-structure energies of the ground state of carbon-like atoms from Z=6 to 8 have been calculated. The results are in close agreement with the experimental data.
黄时中, 马堃, 倪秀波, 胡健, 吴长义. 类碳体系基态能量的精细结构[J]. 原子与分子物理学报, 2008, 25(2): 321. 黄时中, 马堃, 倪秀波, 胡健, 吴长义. Fine-structure of the ground state of carbon-like atoms[J]. Journal of Atomic and Molecular Physics, 2008, 25(2): 321.