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Ho,Yb∶Tb3Ga5O12纳米粉体制备及发光性能研究

Preparation and luminescent properties of Ho,Yb∶Tb3Ga5O12 nano-powder

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摘要

以Tb4O7和Ga2O3(化学计量比为3∶5)、Ho2O3、Yb2O3为原料, 其中Yb3+的掺杂浓度为8at.%, Ho3+的掺杂浓度分别为05at.%、1at.%、15at.%、20at.%, 以碳酸氢铵为沉淀剂, 在1 200 ℃下烧结10 h得到了Ho,Yb∶Tb3Ga5O12(Ho,Yb∶TGG)纳米粉体。对样品进行了XRD物相分析、热重-差热分析、红外光谱分析以及扫描电镜分析、上转换发射光谱分析。实验结果表明, 温度为1 200 ℃下样品平均晶粒尺寸为3810 nm。在泵浦源为980 nm激发下, Ho3+掺杂浓度为15at.%, Yb3+掺杂浓度为8at.%时, 在红、绿、蓝波段范围内出现了明显的上转换发光现象, 并对其形成机理进行了讨论。分析认为, Ho3+由激发态5S2, 5F4向基态5I8跃迁, 实现了绿光输出, 而Ho3+由激发态5F5和5F3向基态5I8跃迁, 分别实现了红光和蓝光输出。

Abstract

With ammonium bicarbonate as the precipitating agent, using Tb4O7, Ga2O3, Ho2O3, Yb2O3 as raw materials(the stoichiometry of Tb4O7 and Ga2O3) is 3∶5 and doping Yb3+(8at.%)/Ho3+(05at.%、1at.%、15at.%、20at.% respectively), Ho,Yb∶Tb3Ga5O12(Ho,Yb∶TGG) nano-powder was sintered at 1 200 ℃ for 10 h to obtain a pure phase. The samples were characterized by XRD, TG-DTA, Infrared Spectroscopy(IRS), Scanning Electron Microscopy(SEM) and upconversion emission spectroscopy. The experimental results show that the average grain size of the samples is 3810 nm under the temperature of 1 200 ℃. When the samples with Yb3+(8at.%)/Ho3+(15at.%) concentrations were used, there was a clear upconversion luminescence in the wavelength rage of blue, green and red by 980 nm LD. The formation mechanism was discussed at the same time. Analyse indicates that Ho3+ transits from excited states 5S2 and 5F4 to ground state 5I8, achieving the launch of green, and it transits from excited states 5F5 and 5F3 to ground state 5I8, achieving the launch of red and blue respectively.

Newport宣传-MKS新实验室计划
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DOI:10.3788/co.20150804.0608

所属栏目:光学功能材料

基金项目:吉林省创新创业训练计划资助项目(No.2014S017)

收稿日期:2015-04-08

修改稿日期:2015-05-15

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徐嘉林:长春理工大学 光电功能材料教育部工程研究中心, 吉林 长春 130022
金维召:长春理工大学 光电功能材料教育部工程研究中心, 吉林 长春 130022
刘旺:长春理工大学 光电功能材料教育部工程研究中心, 吉林 长春 130022
彭海益:长春理工大学 光电功能材料教育部工程研究中心, 吉林 长春 130022
刘贺:长春理工大学 光电功能材料教育部工程研究中心, 吉林 长春 130022
李春:长春理工大学 光电功能材料教育部工程研究中心, 吉林 长春 130022
林海:长春理工大学 光电功能材料教育部工程研究中心, 吉林 长春 130022
刘景和:长春理工大学 光电功能材料教育部工程研究中心, 吉林 长春 130022
曾繁明:长春理工大学 光电功能材料教育部工程研究中心, 吉林 长春 130022

联系人作者:曾繁明(zengfm@126.com)

备注:徐嘉林(1993—), 男, 吉林长春人, 硕士研究生, 主要从事人工晶体及上转换发光材料方面的研究。

【1】王伟.稀土上转换发光材料的研究与应用[J].广州化工, 2014, 42(11): 32-35.
WANG W. Research and application of rare earth up-conversation luminescent matericals[J]. Guangzhou Chemical Industry, 2014, 42(11): 32-35.(in Chinese)

【2】HE J L,ZHOU ZH G,ZHAN H,et al. Intense red fluorescence from Ho/Yb codoped tellurite glasses[J]. J. Non-crystalline Solids,2014,383: 157-160.

【3】章健, 王士维, 安丽琼, 等.980 nm LD激发下 Yb3+,Er3+∶Y2O3纳米晶粉体的上转换发光[J].发光学报, 2005,26(6): 789-793.
ZHANG J,WANG SH W,AN L Q,et al.. Up-conversion luminescence in Yb3+,Er3+∶Y2O3 nano-crystalline powder excited by a 980 nm laser diode[J]. Chin. J. Lumin,2005,26(6): 789-793.(in Chinese)

【4】郭艳艳, 吴杏华, 王殿元, 等.980 nm LD激发下稀土掺杂Gd2Ti207粉末上转换发光[J].中国稀土学报, 2009,27(6): 735-738.
GUO Y Y,WU X H,WANG D Y,et al.. Up-conversion emission in rare earth-doped Gd2Ti2O7 excited by 980nm laser diode[J]. J. Chinese Rare Earth Society,2009,27(6): 735-738.(in Chinese)

【5】徐东勇,臧竞存.上转换激光和上转换发光材料的研究进展[J].人工晶体学报, 2001, 30(2): 209-209.
XU D Y,ZANG J C. Progress of study on up-conversion laser and luminescence materials[J]. J. Synthetic Crystals,2001,30(2): 209-209.(in Chinese)

【6】李新跃, 邓建国, 刘东亮.氧化物掺杂稀土的上转换材料研究进展[J].信阳师范学院校报, 2011, 24(3): 414-420.
LI X Y,DENG J G,LIU D L. Research progress of up-conversion materials of oxide matrix with doped rare earth[J]. J. Xinyang Normal University,2011,24(3): 414-420.(in Chinese)

【7】杨林海, 宋宏伟, 于立新, 等.Y2O3∶Ho/Yb纳米晶的上转换发光性质[J].发光学报, 2004,25(6): 710-714.
YAN L H,SONG H W,YU L X,et al.. Up-conversion luminescence in nano-crystalline Y2O3 Ho/Yb[J]. Chin. J. Lumin,2004,25(6): 710-714.(in Chinese)

【8】成诗恕, 程艳, 赵呈春, 等.Yb, Ho∶YAG晶体的生长及光谱性能[J].人工晶体学报, 2010,39(2): 332-360.
CHENG SH S,CHENG Y,ZHAN CH CH,et al. Growth and spectral properties of Ho,Yb∶YAG crystal[J]. J. Synthetic Crystals,2010,39(2): 332-360.(in Chinese)

【9】KAMINSKII A A,EICHLER H J,REICHE P,et al.. SRS risk potential in Faraday rotator Tb3Ga5O12 crystals for high-peak power lasers[J]. Laser Physics Letters,2005,2(10): 489-492.

【10】李锋锋, 张明熹, 沈毅, 等.溶胶-凝胶法制备YAG∶Ho3+, Yb3+纳米晶[J].稀有金属与硬质合金, 2009,37(4): 1-6.
LI F F,ZHANG M X,SHEN Y,et al.. Sol-Gel synthesis of YAG∶Ho3+,Yb3+, nanocrystal[J]. Rare Metals and Cemented Carbides,2009,37(4): 1-6.(in Chinese)

【11】金晶, 夏海瑞, 孙尚倩, 等.Nd∶YbVO4晶体的拉曼光谱和荧光光谱研究[J].人工晶体学报, 2008,37(6): 1330-1336.
JIN J,XIA H R,SUN SH Q,et al.. Raman Spectroscopy and Fluorescent Spectra Investigation of Nd∶YbVO4 Crystal[J]. J. Synthetic Crystals,2008,37(6): 1330-1336.(in Chinese)

【12】YANG F ZH,YI G SH,CHEN D P,et al.. Synthesis and up-conversion luminescence properties of nanocrystal Yb,Ho Co-doped sodium yttrium fluoride[J]. Chenmical J. Chinese Universities,2009,25(9): 1589-1592.

【13】李静, 王继杨, 苏静, 等.Ho3+,Yb3+∶YAl3(BO3)4晶体的光谱特性[J].光电子激光, 2005, 16(9): 1067-1070.
LI J,WANG J Y,SUN J,et al.. Optical properties of Ho3+,Yb3+∶YAl3(BO3)4 crystal[J]. J. Optoelectronics Laser,2005,16(9): 1067-1070.(in Chinese)

【14】姜丽霞, 孙晶, 于文生, 等.溶胶凝胶低温燃烧法制备Yb, Ho∶Gd3Ga5012纳米粉体[J].硅酸盐通报, 2010,29(6): 1329-1332.
JIANG L X,SUN J,YU W SH,et al. Preparation of Yb,Ho∶Gd3Ga5O12 nano-powdes by Sol-gel low temperature combustion method[J]. J. Am. Ceram. Soc.,2010,29(6): 1329-1332.(in Chinese)

【15】孙海鹰, 张希艳, 王能利, 等.YAG超细粉体的制备与表征[J].硅酸盐通报, 2009, 28(1): 200-203.
SUN H Y,ZHANG X Y,WANG N L,et al.. Synthesis and characterization of YAG superfine powder[J]. Bulletin of the Chinese Ceramic Society,2009,28(1): 200-203.(in Chinese)

【16】李江, 潘裕柏, 张俊计, 等.共沉淀法制备钇铝石榴石(YAG)纳米粉体[J].硅酸盐学报, 2003, 31(5): 490-493
LI J,PAN Y B,ZHANG J J,et al.. Synthesizing Yttrium Aluminum Garnet(YAG) nano-powder by coprecipitation method[J]. J. Chinese Ceramic Society,2003,31(5): 490-493.(in Chinese)

【17】CHEN D Y,JORDAN E H,GELL M. Sol-gel combustion synthesis of nano-crystalline YAG powder from metal-organic precursors[J]. J. American Ceramic Society,2008,91(8): 2759-2762.

【18】QIU H L. Controlled Synthesis and up-conversion luminescence of lanthanide nanocrystals[D]. Harbin: Harbin Institute of Technology,2010.

【19】KIRYANOV A V,ABOITES V,BELOVOLOV A M,et al.. Visible-to-near-IR luminescence at stepwise up-conversion in Yb,Ho∶GGG under IR diode pumping[J]. J. Luminescence,2003(102-103): 715-721.

引用该论文

XU Jia-lin,JIN Wei-zhao,LIU Wang,PENG Hai-yi,LIU He,LI Chun,LIN Hai,LIU Jing-he,ZENG Fan-ming. Preparation and luminescent properties of Ho,Yb∶Tb3Ga5O12 nano-powder[J]. Chinese Optics, 2015, 8(4): 608-614

徐嘉林,金维召,刘旺,彭海益,刘贺,李春,林海,刘景和,曾繁明. Ho,Yb∶Tb3Ga5O12纳米粉体制备及发光性能研究[J]. 中国光学, 2015, 8(4): 608-614

被引情况

【1】刘金金,徐明祥. 氧化硅薄膜中掺杂Tb3+离子的发光敏化. 发光学报, 2016, 37(12): 1464-1470

【2】刘晓辉,马世童,郑克志,,秦伟平. 基于合作能量传递的Sm2+离子上转换发光. 发光学报, 2017, 38(11): 1413-1419

【3】赖凤琴,李嘉鹏,吴有福生,胡美兰,肖青辉,姚庆林,夏李斌,叶信宇,游维雄. 烧结温度和掺杂浓度对Y4Zr3O12∶ Eu3+荧光粉发光性质的影响. 发光学报, 2017, 38(11): 1436-1442

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