We propose a novel waveguide design of a polarization-maintaining few mode fiber (PM-FMF) supporting ≥10 non-degenerate modes, utilizing a central circular air hole and a circumjacent elliptical-ring core. The structure endows a new degree of freedom to adjust the birefringence of all the guided modes, including the fundamental polarization mode. Numerical simulations demonstrate that, by optimizing the air hole and elliptical-ring core, a PM-FMF supporting 10 distinctive polarization modes has been achieved, and the effective index difference Δneff between the adjacent guided modes could be kept larger than 1.32×10 4 over the whole C+L band. The proposed fiber structure can be flexibly tailored to support an even larger number of modes in PM-FMF (14-mode PM-FMF has been demonstrated as an example), which can be readily applicable to a scalable mode division multiplexing system.