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Exciton binding energy and effective mass of CsPbCl3: a magneto-optical study

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Abstract

High magnetic field spectroscopy has been performed on lead chloride-based perovskite, a material that attracts significant interest for photovoltaic and photonic applications within the past decades. Optical properties being mainly driven by the exciton states, we have measured the fundamental parameters, such as the exciton binding energy, effective mass, and dielectric constant. Among the inorganic halide perovskites, CsPbCl3 owns the largest exciton binding energy and effective mass. This blue emitting compound has also been compared with lower band gap energy perovskites and other semiconducting phases, showing comparable band gap dependences for binding energy and Bohr radius.

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DOI:10.1364/PRJ.401872

所属栏目:Research Articles

基金项目:Ministry of Education—Singapore10.13039/501100001459; National Science Centre Poland; Agence Nationale de la Recherche10.13039/501100001665;

收稿日期:2020-07-09

录用日期:2020-08-11

网络出版日期:2020-08-12

作者单位    点击查看

Michal Baranowski:Department of Experimental Physics, Faculty of Fundamental Problems of Technology, Wroclaw University of Science and Technology, Wroclaw, Poland
Paulina Plochocka:Department of Experimental Physics, Faculty of Fundamental Problems of Technology, Wroclaw University of Science and Technology, Wroclaw, Poland;Laboratoire National des Champs Magnétiques Intenses, UPR 3228, CNRS-UGA-UPS-INSA, Grenoble and Toulouse, France
Rui Su:Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore, Singapore
Laurent Legrand:Sorbonne Université, CNRS-UMR 7588, Institut des NanoSciences de Paris, INSP, Paris, France
Thierry Barisien:Sorbonne Université, CNRS-UMR 7588, Institut des NanoSciences de Paris, INSP, Paris, France
Frederick Bernardot:Sorbonne Université, CNRS-UMR 7588, Institut des NanoSciences de Paris, INSP, Paris, France
Qihura Xiong:Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore, Singapore
Christophe Testelin:Sorbonne Université, CNRS-UMR 7588, Institut des NanoSciences de Paris, INSP, Paris, France
Maria Chamarro:Sorbonne Université, CNRS-UMR 7588, Institut des NanoSciences de Paris, INSP, Paris, France

联系人作者:Maria Chamarro(maria.chamarro@insp.jussieu.fr)

备注:Ministry of Education—Singapore10.13039/501100001459; National Science Centre Poland; Agence Nationale de la Recherche10.13039/501100001665;

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引用该论文

Michal Baranowski, Paulina Plochocka, Rui Su, Laurent Legrand, Thierry Barisien, Frederick Bernardot, Qihura Xiong, Christophe Testelin, and Maria Chamarro, "Exciton binding energy and effective mass of CsPbCl3: a magneto-optical study," Photonics Research 8(10), A50 (2020)

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