刘海毅 1,2齐鹏飞 1,2,*
作者单位
摘要
1 南开大学现代光学研究所,天津 300350
2 天津市微尺度光学信息技术科学重点实验室,天津 300350
上转换发光即发射光子能量高于激发光子能量的反斯托克斯过程,可以有效实现能量重整与转化,在生物成像、太阳能电池、光催化及光制冷等方面有着巨大应用前景。作为后摩尔时代战略性新材料,二维材料由于激子偶极矩强度大、线宽窄、无序性低、束缚能高等优势,为实现室温高效激子上转换发光创造了有利条件,近年来吸引了研究者的广泛兴趣。本文首先介绍实现光子上转换的发光机制,包括声子辅助、双光子吸收、俄歇复合等途径,进而梳理基于六方氮化硼、单层过渡金属二硫化物、二维钙钛矿等典型二维材料体系的上转换发光效应研究,同时针对上转换发光效率低的问题,讨论对二维材料上转换发光的调控和增强方式,最后展望二维材料体系激子上转换发光效应的应用前景。
上转换发光 材料 二维材料 激子 非线性光学 
激光与光电子学进展
2024, 61(3): 0316007
作者单位
摘要
1 山东师范大学物理与电子科学学院,光场调控及应用中心,山东省光学与光子器件技术重点实验室,山东 济南 250358
2 华东师范大学与山东师范大学光调控科学与光子集成芯片联合研究中心,上海 200241
采用溶液法合成了二维硫铟锌纳米花,并测量了其可饱和吸收参数,其中,饱和强度为675 MW/cm2,调制深度为7.8%。通过搭建1 μm 全固态激光器,获得最大输出功率为240 mW、最大重复频率为629.08 kHz、最小脉冲宽度为388 ns、相应的单脉冲能量为0.38 μJ、峰值功率为0.98 W的脉冲激光。结果表明,由于硫空位的存在,硫铟锌纳米花能够吸收能量低于其带宽的光子,在近红外区域,表现出良好的可饱和吸收特性,且在激光器中,能够获得高重复频率和短脉冲宽度的激光输出。因此,基于硫铟锌纳米材料的可饱和吸收体在调Q脉冲激光器中具有广阔的应用前景。
非线性光学 脉冲激光 可饱和吸收体 二维材料 硫空位 硫铟锌 
光学学报
2024, 44(4): 0419001
作者单位
摘要
1 重庆大学光电工程学院光电技术及系统教育部重点实验室,重庆 400044
2 中国科学院重庆绿色智能技术研究院微纳制造与系统集成研究中心,重庆 400714
表面增强红外吸收光谱技术能够将红外光波高度局域在探测分子周围,极大增强光波与分子的相互作用,为实现微弱分子红外振动光谱信号的高灵敏探测提供了新思路。其中,二维材料极化激元由于具有高度局域化光场和低固有损耗等独特性质,为表面增强红外光谱提供了一种有效的方案。本文综述了二维材料极化激元增强红外光谱技术的研究进展:首先从不同材料体系出发介绍极化激元基本特性,论述极化激元与分子模式耦合机理;在此基础上总结二维材料极化激元增强红外光谱技术的几个重要研究方向,主要包括等离激元增强红外光谱技术、声子极化激元增强红外光谱技术和近场红外光谱增强技术;最后展望极化激元增强红外光谱技术未来可能的发展方向。
表面增强光谱 二维材料 等离激元 声子极化激元 红外光谱 
激光与光电子学进展
2024, 61(3): 0330001
Author Affiliations
Abstract
1 Centre for Micro Nano Systems, School of Information Science and Technology (SIST), Fudan University, Shanghai 200433, China
2 Zhangjiang Laboratory, Shanghai 201210, China
The heterogeneous integration of photonic integrated circuits (PICs) with a diverse range of optoelectronic materials has emerged as a transformative approach, propelling photonic chips toward larger scales, superior performance, and advanced integration levels. Notably, two-dimensional (2D) materials, such as graphene, transition metal dichalcogenides (TMDCs), black phosphorus (BP), and hexagonal boron nitride (hBN), exhibit remarkable device performance and integration capabilities, offering promising potential for large-scale implementation in PICs. In this paper, we first present a comprehensive review of recent progress, systematically categorizing the integration of photonic circuits with 2D materials based on their types while also emphasizing their unique advantages. Then, we discuss the integration approaches of 2D materials with PICs. We also summarize the technical challenges in the heterogeneous integration of 2D materials in photonics and envision their immense potential for future applications in PICs.
two-dimensional materials silicon photonics heterogeneous integration photonic integrated circuits 
Chinese Optics Letters
2023, 21(11): 110007
作者单位
摘要
复旦大学 信息科学与工程学院,上海 200433
中波长红外(Mid-wavelength infrared,MWIR)光电器件可用于热成像、光通信和气体传感等多个领域。二维黑磷(Black phosphorus,BP)在中波长红外范围显示出独特的优点,其所有厚度下都具有直接带隙和高迁移率的特点使其在中红外光电器件应用方面具有很大的潜力。由于皱褶的晶格结构,黑磷有较强的面内各向异性,可应用于线偏振光电器件。此外,黑磷通过掺杂、应力调控和异质堆叠等多种方式可以实现室温下中红外波段范围内的各种功能性光电器件。本文综述了黑磷的晶体和能带结构及其各向异性的光学性质,并结合近年来在偏振方向敏感的光电探测器和光谱可调控等功能性光电器件方面的应用研究进展,总结了该材料在实际应用中的主要优势和面临的重要问题。最后对二维黑磷在中红外光电器件应用领域的发展趋势进行了展望。
黑磷 二维材料 中波长红外 光电器件 black phosphorus two-dimensional materials mid-wavelength infrared optoelectronic devices 
发光学报
2023, 44(6): 995
作者单位
摘要
东南大学 物理学院, 江苏 南京 211100
二维(2D)半导体材料Bi2O2Se由于具有独特的晶体结构与能带结构、超高的载流子迁移率和优异的稳定性,在紫外-可见-近红外光谱区的高性能电子与光电应用领域有着广阔的前景。本文综述了Bi2O2Se的材料制备与光学表征最新研究进展:首先,介绍了2D Bi2O2Se的制备方法及生长机理,包括化学气相沉积法(CVD)、湿化学工艺、分子束外延法(MBE)和脉冲激光沉积法(PLD)等;其次,介绍了其晶体结构和电子能带结构的基本性质;接下来,通过稳态光谱的研究,可以对2D Bi2O2Se随厚度变化的带隙等物理性质进行研究;通过研究其晶体振动模式,可进一步研究2D Bi2O2Se材料的缺陷形态、温度系数与热导率;此外,超快光谱技术也可以帮助研究2D Bi2O2Se材料内部载流子的弛豫过程与输运性能;最后,简述了当前Bi2O2Se研究面临的挑战与应用的前景。
二维材料 Bi2O2Se 合成与制备 光学表征 two-dimensional materials Bi2O2Se synthesis and preparation optical characterization 
中国光学
2023, 16(1): 24
张家辉 1,2王秀翃 1,2,*
作者单位
摘要
1 北京市激光应用技术工程技术研究中心,跨尺度激光成型制造技术教育部重点实验室,北京工业大学材料与制造学部,北京 100124
2 北京工业大学材料与制造学部激光工程研究院,北京 100124
二维材料在许多方面相较于常规材料的优异性能,引发了研究人员对于二维材料的广泛关注。目前二维材料已经成为了各个领域内的研究热点,被广泛应用于生物医学、电子、光电子和催化等诸多方面。本文主要就二维材料在生物医学领域内的光学传感应用做了总结与讨论。主要论述了二维材料的产生和发展、优缺点,基于二维材料的光学生物传感器类型、原理及其制造方法,以及这些传感器在单细胞、RNA、蛋白质分子高灵敏探测技术上的一些成果,并结合这些成果简要分析了利用二维材料的实验方案相较于传统方法的一些优势。最后对二维材料的发展现状做了简要总结,并对其未来发展作出了展望。
二维材料 光学生物传感 表面等离子体共振 荧光淬灭 表面增强拉曼散射 
激光与光电子学进展
2023, 60(11): 1106016
Author Affiliations
Abstract
1 School of Integrated Circuits, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, China
2 Hubei Yangtze Memory Laboratories, Wuhan 430205, China
Inspired by the recently predicted 2D MX2Y6 (M = metal element; X = Si/Ge/Sn; Y = S/Se/Te), we explore the possible applications of alkaline earth metal (using magnesium as example) in this family based on the idea of element replacement and valence electron balance. Herein, we report a new family of 2D quaternary compounds, namely MgMX2Y6 (M = Ti/Zr/Hf; X = Si/Ge; Y = S/Se/Te) monolayers, with superior kinetic, thermodynamic and mechanical stability. In addition, our results indicate that MgMX2Y6 monolayers are all indirect band gap semiconductors with band gap values ranging from 0.870 to 2.500 eV. Moreover, the band edges and optical properties of 2D MgMX2Y6 are suitable for constructing multifunctional optoelectronic devices. Furthermore, for comparison, the mechanical, electronic and optical properties of In2X2Y6 monolayers have been discussed in detail. The success of introducing Mg into the 2D MX2Y6 family indicates that more potential materials, such as Ca- and Sr-based 2D MX2Y6 monolayers, may be discovered in the future. Therefore, this work not only broadens the existing family of 2D semiconductors, but it also provides beneficial results for the future.Inspired by the recently predicted 2D MX2Y6 (M = metal element; X = Si/Ge/Sn; Y = S/Se/Te), we explore the possible applications of alkaline earth metal (using magnesium as example) in this family based on the idea of element replacement and valence electron balance. Herein, we report a new family of 2D quaternary compounds, namely MgMX2Y6 (M = Ti/Zr/Hf; X = Si/Ge; Y = S/Se/Te) monolayers, with superior kinetic, thermodynamic and mechanical stability. In addition, our results indicate that MgMX2Y6 monolayers are all indirect band gap semiconductors with band gap values ranging from 0.870 to 2.500 eV. Moreover, the band edges and optical properties of 2D MgMX2Y6 are suitable for constructing multifunctional optoelectronic devices. Furthermore, for comparison, the mechanical, electronic and optical properties of In2X2Y6 monolayers have been discussed in detail. The success of introducing Mg into the 2D MX2Y6 family indicates that more potential materials, such as Ca- and Sr-based 2D MX2Y6 monolayers, may be discovered in the future. Therefore, this work not only broadens the existing family of 2D semiconductors, but it also provides beneficial results for the future.
two-dimensional materials MgMX2Y6 monolayer In2X2Y6 monolayer semiconductor first-principles calculations 
Journal of Semiconductors
2023, 44(4): 042101
Author Affiliations
Abstract
1 Cornell University, Department of Physics, Ithaca, New York, United States
2 Cornell University, School of Applied and Engineering Physics, Ithaca, New York, United States
On-demand modification of the electronic band structures of high-mobility two-dimensional (2D) materials is of great interest for various applications that require rapid tuning of electrical and optical responses of solid-state devices. Although electrically tunable superlattice (SL) potentials have been proposed for band structure engineering of the Dirac electrons in graphene, the ultimate goal of engineering emergent quasiparticle excitations that can hybridize with light has not been achieved. We show that an extreme modulation of one-dimensional (1D) SL potentials in monolayer graphene produces ladder-like electronic energy levels near the Fermi surface, resulting in optical conductivity dominated by intersubband transitions (ISBTs). A specific and experimentally realizable platform comprising hBN-encapsulated graphene on top of a 1D periodic metagate and a second unpatterned gate is shown to produce strongly modulated electrostatic potentials. We find that Dirac electrons with large momenta perpendicular to the modulation direction are waveguided via total internal reflections off the electrostatic potential, resulting in flat subbands with nearly equispaced energy levels. The predicted ultrastrong coupling of surface plasmons to electrically controlled ISBTs is responsible for emergent polaritonic quasiparticles that can be optically probed. Our study opens an avenue for exploring emergent polaritons in 2D materials with gate-tunable electronic band structures.
band structure engineering two-dimensional materials polaritons plasmons intersubband transitions 
Advanced Photonics
2023, 5(2): 026004
李嘉辉 1,2,*练成 1,2刘洪来 1,2
作者单位
摘要
1 华东理工大学化学与分子工程学院, 上海 200237
2 华东理工大学化工学院联合国家重点实验室, 上海 200237
人类日常生活中使用的化学化工产品约有80%的生产制造过程中涉及非均相催化反应, 如何缩短催化剂开发周期, 高效筛选性能优异的催化剂成为一大重要议题。在诸多催化剂中, 二维材料因其独特的结构与电子特性备受关注, 从种类繁多的二维材料中筛选出满足特定反应需求的类型需要明晰催化剂结构与功能的关系。描述符能够关联起催化剂的结构性质、电子性质与催化剂的性能, 通过描述符, 催化剂的构效关系能够被揭示与衡量。结构描述符预测二维碳材料催化活性时性能较好, 电子描述符较之于结构描述符, 与催化反应性能的特征参数更为匹配, 而融合两者特色的二元描述符是催化剂性能描述符未来发展的重要方向。在大数据的时代背景下, 描述符的发展逐渐与机器学习等新兴方法融合, 包含多维度参数的性能预测模型崭露头角, 随着人工智能技术的更迭, 大数据驱动的性能描述符将助力二维材料催化剂的蓬勃发展。
描述符 二维材料 d带中心 密度泛函理论 机器学习 descriptor two-dimensional materials d-band center density functional theory machine learning 
硅酸盐学报
2023, 51(2): 520

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