太原理工大学 纳米能源与器件研究中心, 山西 太原 030024
该文通过两步水热法制备了钛酸钡纳米线(BTO NWs), 采用旋涂法与聚偏氟乙烯(PVDF)复合制备BTO NWs/PVDF复合薄膜。系统地研究了水热反应中不同NaOH浓度、不同反应时间及不同BTO NWs掺杂量对BTO NWs/PVDF复合薄膜压电输出性能的影响, 并与商用钛酸钡纳米球(BTO NPs)制备的BTO NPs/PVDF复合薄膜进行了压电性能对比。结果表明, 当NaOH浓度为10 mol/L, 反应时间为10 h时, BTO NWs/PVDF复合薄膜开路电压和短路电流分别可达5.42 V和1.81 μA。当BTO NWs掺杂量(质量分数)为20%时, 复合压电薄膜的开路电压可达9.34 V, 短路电流可达2.15 μA, 分别是BTO NPs/PVDF复合薄膜输出电压和电流的1.92倍和1.49倍。当负载电阻值为5 MΩ时, BTO NWs/PVDF复合薄膜输出功率可达1.44 μW。经过4 000次循环敲击测试, BTO NWs/PVDF复合薄膜表现出良好的机械稳定性, 其有望在自供电器件、柔性可穿戴电子设备等领域得到广泛应用。
钛酸钡纳米线(BTO NWs) 聚偏氟乙烯(PVDF) 复合压电薄膜 输出特性 barium titanate nanowires (BTO NWs) polyvinylidene fluoride (PVDF) composite piezoelectric films output characteristics
红外与激光工程
2023, 52(10): 20230433
1 山西大学物理电子工程学院,山西 太原 030006
2 山西大学激光光谱研究所量子光学与光量子器件国家重点实验室,山西 太原 030006
3 山西大学极端光学协同创新中心,山西 太原 030006
本文采用多级方法(MPM)对涂覆石墨烯的双椭圆和圆柱并行纳米线波导的基模的有效折射率进行了计算,并采用有限元法(FEM)对计算结果进行了验证。本文研究了两种计算方法的结果之间的相对误差随MPM展开项数的最大值、工作波长、费米能、椭圆柱形纳米线的半长轴及半短轴、纳米线表面之间的横向间距,以及圆柱形纳米线的相对高度等变化的规律。通过对照计算结果得到以下规律:随着级数展开项数增大,MPM的结果越接近FEM的结果;随着工作波长和费米能增大,有效折射率实部和虚部的相对误差均增大;随着圆柱形电介质纳米线的半径和椭圆柱形纳米线的半长轴增大,有效折射率实部的相对误差增大,而其虚部的相对误差减小;随着椭圆柱形纳米线的半短轴增大,有效折射率实部的相对误差减小,而其虚部的相对误差增大;随着纳米线表面之间的横向间距和圆柱形纳米线的相对高度增大,有效折射率实部和虚部的相对误差均减小。这些现象均可以通过场分布得到解释。在本文的计算范围内,相对误差均保持在10-3量级。该研究工作为混合型电介质并行纳米线波导的设计、制作和应用提供了理论基础。
石墨烯 纳米线 波导 多极方法 有限元法 graphene nanowires waveguides multipole method finite element method 光学学报
2023, 43(22): 2213002
武汉理工大学,材料复合新技术国家重点实验室,武汉 430070
近年来的能源危机和环境污染问题加速了储能领域的快速发展。一维纳米材料,尤其是纳米线材料所具有的高长径比特点使其具有独特的电子离子输运性质,在储能领域的应用中具有极大的潜能。本文以本课题组在纳米线储能材料与器件领域的研究成果为基础,结合国内外同行的前沿研究进展,从纳米线材料的结构设计与合成、纳米线材料在电池中的应用和纳米线微纳器件3个方面进行综述。最后,对于未来进一步探索和发展基于纳米线的电化学储能材料与器件的前景进行展望。
纳米线 结构构筑 储能电池 微纳器件 nanowires structure construction energy storage batteries micro-nano devices

Author Affiliations
Abstract
Miniaturized light sources at telecommunication wavelengths are essential components for on-chip optical communication systems. Here, we report the growth and fabrication of highly uniform p-i-n core-shell InGaAs/InP single quantum well (QW) nanowire array light emitting diodes (LEDs) with multi-wavelength and high-speed operations. Two-dimensional cathodoluminescence mapping reveals that axial and radial QWs in the nanowire structure contribute to strong emission at the wavelength of ~1.35 and ~1.55 μm, respectively, ideal for low-loss optical communications. As a result of simultaneous contributions from both axial and radial QWs, broadband electroluminescence emission with a linewidth of 286 nm is achieved with a peak power of ~17 μW. A large spectral blueshift is observed with the increase of applied bias, which is ascribed to the band-filling effect based on device simulation, and enables voltage tunable multi-wavelength operation at the telecommunication wavelength range. Multi-wavelength operation is also achieved by fabricating nanowire array LEDs with different pitch sizes on the same substrate, leading to QW formation with different emission wavelengths. Furthermore, high-speed GHz-level modulation and small pixel size LED are demonstrated, showing the promise for ultrafast operation and ultracompact integration. The voltage and pitch size controlled multi-wavelength high-speed nanowire array LED presents a compact and efficient scheme for developing high-performance nanoscale light sources for future optical communication applications.
InGaAs/InP quantum well nanowires LEDs Opto-Electronic Science
2023, 2(5): 230003

Author Affiliations
Abstract
1 State Key Laboratory of Precision Spectroscopy, School of Physics and Electronic Science, East China Normal University, Shanghai 200062, China
2 Huawei Technologies Co, Ltd., Bantian Longgang District, Shenzhen 518129, China
3 Collaborative Innovation Center of Extreme Optics, Shanxi University, Taiyuan 030006, China
This paper reports the fabrication of regular large-area laser-induced periodic surface structures (LIPSSs) in indium tin oxide (ITO) films via femtosecond laser direct writing focused by a cylindrical lens. The regular LIPSSs exhibited good properties as nanowires, with a resistivity almost equal to that of the initial ITO film. By changing the laser fluence, the nanowire resistances could be tuned from 15 to 73 kΩ/mm with a consistency of ±10%. Furthermore, the average transmittance of the ITO films with regular LIPSSs in the range of 1200–2000 nm was improved from 21% to 60%. The regular LIPSS is promising for transparent electrodes of nano-optoelectronic devices—particularly in the near-infrared band.
transparent nanowires periodic surface nanostructures femtosecond laser direct writing ITO film anisotropic electrical conductivity Opto-Electronic Science
2023, 2(1): 220002

Author Affiliations
Abstract
1 Nanjing University of Posts and Telecommunications, College of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), Nanjing, China
2 Nanjing University, School of Electronic Science and Engineering, Nanjing, China
The AlGaN/GaN p–n junction has received extensive attention due to its capability of rapid photogenerated carrier separation in photodetection devices. The AlGaN/GaN heterojunction nanowires (NWs) have been especially endowed with new life for distinctive transport characteristics in the photoelectrochemical (PEC) detection field. A self-powered PEC ultraviolet photodetector (PEC UV PD) based on the p-AlGaN/n-GaN heterojunction NW is reported in this work. The n-GaN NW layer plays a crucial role as a current flow hub to regulate carrier transport, which mainly acts as a light absorber under 365 nm and carrier recombination layer under 255 nm illumination, which can effectively modulate photoresponsivity at different wavelengths. Furthermore, by designing the thicknesses of the NW layer, the photocurrent polarity reversal was successfully achieved in the constructed AlGaN/GaN NW PEC UV PD at two different light wavelengths. In addition, by combining with platinum decoration, the photoresponse performance could be further enhanced. Our work provides insight into transport mechanisms in the AlGaN/GaN NW PEC system, and offers a feasible and comprehensive strategy for further exploration of multifunctional optoelectronic devices.
GaN nanowires ultraviolet detection photoelectrochemistry photoresponse Advanced Photonics Nexus
2023, 2(3): 036003
为了获得导电岛微电极系统中纳米线的介电组装特性, 基于平面微电极对和导电岛微电极系统, 进行了两种系统中纳米线操控的对比实验。分别建立了平面微电极对和导电岛微电极系统的纳米线介电组装模型, 探究了两种模型下的纳米线从初始位置到最终桥接上微间隙过程中的运动轨迹; 分析了导电岛微电极系统中纳米线所受的介电泳力、交流电热流以及两者合作用的电动力学行为。导电岛微电极系统对纳米线有着较强的介电俘获作用, 导电岛的加入能够让纳米线更好地俘获到微间隙; 同时纳米线的介电组装会受到频率的影响, 当频率达到翻转频率, 在微间隙上方产生的微流体漩涡能够把远场区域纳米线输送到组装区, 使得纳米线受到正介电泳力的作用而被组装至微间隙。
平面微电极对 导电岛微电极系统 介电泳 交流电热流 纳米线 planar microelectrode pairs conductive island microelectrode system dielectrophoresis alternating current electrothermal flow nanowires
1 School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, China
2 School of Science, Shenyang Ligong University, Shenyang 110159, China
3 Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, China
Supercapacitor Co3O4@NiMoO4 nanowires Specific capacitance Energy density Frontiers of Optoelectronics
2022, 15(2): s12200