原子与分子物理学报, 2003, 20 (4): 561, 网络出版: 2006-05-19
Theoretical study of the intensity of chemically induce dynamic electron polarization of radical-triplet pairs
Theoretical study of the intensity of chemically induce dynamic electron polarization of radical-triplet pairs
化学诱导力学电子极化 密度矩阵 电子自旋 三重态分子 基本三重态对波函数 Chemically induced dynamic eletron polarization RTPM Density Matrix RTPM
摘要
Abstract
Considering the interaction between encited triplet molecule and cloublet radical,based on the second-order perturbation theroy and the motion equation of density matrix,the polarzation intersity of RTPM were theoretically calculated with the overpopulated doublet spin states and quartet spin states of radical0triplet paris as initial conditions the radical result from the zero-field-splitting(zfs)and the multiplet A/E and E/A polarization result from hyperfine (hf) interactions of the triplet molcule,The hyperfine ralated A+A/E or E+E/A CIDEP on the radical were the overpopulation of the net abscrptive or emissive polarization and multiple A/E or E/A polarization.
XUXin-sheng, ZHANGXiao-yi, ZHANGWei-Jun, CUIZhi-feng, LUTong-xing. Theoretical study of the intensity of chemically induce dynamic electron polarization of radical-triplet pairs[J]. 原子与分子物理学报, 2003, 20(4): 561. XUXin-sheng, ZHANGXiao-yi, ZHANGWei-Jun, CUIZhi-feng, LUTong-xing. Theoretical study of the intensity of chemically induce dynamic electron polarization of radical-triplet pairs[J]. Journal of Atomic and Molecular Physics, 2003, 20(4): 561.
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