为了实现对室内微量有毒气体实时监测, 提高基于特征光谱检测方法的测量精度, 提出了特征波长过滤窗的方法。 将高浓度的待测气体作过滤窗, 标准空气作参考窗, 气室充待测浓度的待测气体, 采用组合测量得到的多组光谱进行差分、 相关等数据处理求解气室中待测气体的浓度。 实验显示, 采用WQF-520-FTIR型红外光谱仪得到癸二酸二丙脂红外吸收谱线主要有四条： 3 385.26, 3 417.64, 5 797.11和8 561.65 nm, 分别对应的吸光度为1.520 0, 1.542 1, 2.431 8和1.352 6。 对应的可检测的最小含量为50×10-9, 而采用特征波长过滤窗的方法波长位置可实现10-4 nm量级的对准, 在确定待测气体含量量级的条件下, 可检测的最小含量为5×10-9, 灵敏度提高约10倍。 该方法具有高灵敏度、 无中毒、 可实时检测等优点。

In order to realize the indoor micro noxious gas real-time monitor, and enhance measuring accuracy based on the characteristic spectrum examination method, a characteristic wavelengths filtration window was designed, in which the container is full with the highly concentrated testing gas. The container with the highly concentrated testing gas was used as the filtration window, the standard air as the reference window, the air chamber sufficient testing gas for testing density. The experiment demonstrated that using the WQF-520-FTIR infrared spectroscope to obtain the infrared absorption spectrum of dipropyl sebacate, there were mainly four characteristic wavelength lines: 3.385 26, 3.417 64, 5.797 11, and 8.561 65 μm, and the corresponding extinction was 1.520 0, 1.542 1, 2.431 8 and 1.352 6 respectively. The smallest content examined was 50 ppb, but using the characteristic wavelengths filtration window, the method could realize the 10-4 nm magnitude alignment. The sensitivity was enhanced nearly 10 times, and the characteristic wavelengths filtration window method has the merits of high sensitivity, no discontinuity, real-time examination, and so on.Dipropyl sebacate