发光学报, 2011, 32 (6): 581, 网络出版: 2011-06-24
基于1,3,5-tri(9H-carbazol-9-yl)benzene主体材料的高效蓝色电致磷光器件
Highly Efficient Blue Phosphorescent OLEDs Based on 1,3,5-tri(9H-carbazol-9-yl)benzene Host Material
光学器件 高效蓝色磷光器件 双发光层 主体材料TCzP physical optics phosphorescent organic light emitting diodes double emitting-layer TCzP
摘要
以1,3,5-tri(9H-carbazol-9-yl)benzene (TCzP)为主体材料,制备了FIrpic掺杂的高效有机电致蓝光双发光层器件,最大亮度为11 957 cd/m2; 最大电流效率为18.8 cd/A; 色坐标为(0.17,0.37); 光谱峰值位于472 nm,在496 nm处有一肩峰; 即使在1 000 cd/m2 下,其效率仍为13.5 cd/A。研究结果表明: 作为主体材料,较高的三重态能量和较高的带隙对于获得高效蓝色磷光器件非常重要。
Abstract
Hightly efficient blue phosphorescent organic light emitting diodes(OLEDs) based on a host material 1,3,5-tri(9H-carbazol-9-yl)benzene (TCzP) doped (iridium(Ⅲ)[bis(4,6-difluorophenyl)-pyridinato-N, C2′]picolinate) (FIrpic) were fabricated, and a double-emitting layer device was also manufactured. The maximum brightness of 11 957 cd/m2, peak current efficiency of 18.8 cd/A with Commission Internationale de LEclairage (CIE) coordinates of (0.17, 0.37) were obtained. The emission peak wavelength of 472 nm with its shoulder peaking at 496 nm were observed. Even at high brightness of 1 000 cd/m2, the current efficiency remains 13.5 cd/A. The experimental results indicate that high triplet energy and hole mobility for a host material are very important to achieve highly efficient blue phosphorescent device.
孙军, 张玉祥, 梅学义, 张宏科, 薛震, 何海晓, 逯璐, 高昌轩. 基于1,3,5-tri(9H-carbazol-9-yl)benzene主体材料的高效蓝色电致磷光器件[J]. 发光学报, 2011, 32(6): 581. SUN Jun, ZHANG Yu-xiang, MEI Xue-yi, ZHANG Hong-ke, XUE Zhen, HE Hai-xiao, LU Lu, GAO Chang-xuan. Highly Efficient Blue Phosphorescent OLEDs Based on 1,3,5-tri(9H-carbazol-9-yl)benzene Host Material[J]. Chinese Journal of Luminescence, 2011, 32(6): 581.