Spurious-free dynamic range (SFDR) limited by intermodulation distortions is a usually accepted measure for dynamic performance of a photonic time-stretched analog-to-digital converter (ADC). In this paper, SFDR improvement in a photonic time-stretched ADC based on third-order predistortion is proposed. The third-order predistortion is achieved optically within an integrated dual-parallel Mach–Zehnder modulator (DPMZM). The mechanism of SFDR improvement with third-order predistortion in the DPMZM is theoretically analyzed. Compared with a conventional scheme without predistortion, the experimental results show that the SFDR improvement of ～26 dB in the proposed scheme is proved.