激光与光电子学进展, 2016, 53 (8): 082302, 网络出版: 2016-09-12
提高有机发光二极管发光性能的阳极修饰方法 下载: 576次
Anode Modification Method for Improving Light Emission Performance of Organic Light Emitting Diode
光学器件 有机发光二极管 缓冲层 发光亮度 电流效率 optical devices organic light emitting diodes buffer layer luminance current efficiency
摘要
通过在有机发光二极管(OLED)的阳极与空穴传输层NPB之间加入m-MTDATA作为缓冲层来研究缓冲层对器件性能的影响。制备了ITO/m-MTDATA(d nm)/NPB(40-d nm)/Alq3(70 nm)/LiF(0.5 nm)/Al(40 nm)、ITO/ MoO3 (15 nm)/NPB(25 nm)/Alq3 (70 nm)/LiF(0.5 nm)/Al(40 nm)结构的器件,研究不同m-MTDATA厚度对OLED发光亮度、电流密度、电流效率等性能的影响。实验发现,当缓冲层的厚度为15 nm时,器件的启亮电压从未加缓冲层的13 V降到了9 V,最大发光亮度从未加缓冲层的5900 cd/m2增加到16300 cd/m2,是原来的2.76倍。最高的电流效率也由未加缓冲层的1.8 cd/A变为3.5 cd/A,是原来的1.94倍。然后在器件的氧化铟锡(ITO)与NPB之间插入了厚度为15 nm的MoO3缓冲层。与同厚度的m-MTDATA器件相比,插入MoO3缓冲层器件的启亮电压降低为8 V,最大亮度为13320 cd/m2,最大电流密度为6030.74 A/m2,最大的电流效率为3.06 cd/A。
Abstract
This research investigates the effect of buffer layer on the performance of organic light emitting diodes (OLED) by adding m-MTDATA as buffer layer between anode and hole transport layer NPB. The devices with ITO/m-MTDATA(d nm)/NPB(40-d nm)/Alq3(70 nm)/LiF(0.5 nm)/Al(40 nm) and ITO/ MoO3 (15 nm)/NPB(25 nm)/Alq3(70 nm)/LiF(0.5 nm)/Al(40 nm) structures are prepared. The effects of m-MTDATA thickness on OLED brightness, current density, current efficiency and other properties are studied. It is found that the turn-on voltage of the device reduces from 13 V to 9 V when the thickness of the buffer layer is 15nm, and the maximum brightness of the device increases from 5900 cd/m2 to 16300 cd/m2, which is about 2.76 times as much as that of the device without buffer layer. The highest current efficiency also increases from 1.8 cd/A to 3.5 cd/A, which is 1.94 times as much as the device without buffer layer. Then the MoO3 buffer layer with the thickness of 15 nm is inserted in the device as a buffer layer between indium tin oxide(ITO) and NPB. Compared to m-MTDATA device with the same thickness, the turn-on voltage of the device with MoO3 buffer layer declines to 8 V, the maximum brightness is 13320 cd/m2, the maximum current density is 6030.74 A/m2, and the maximum current efficiency is 3.06 cd/A.
夏树针, 王文军, 杜倩倩, 李淑红, 张栋, 高学喜, 王青如, 张丙元. 提高有机发光二极管发光性能的阳极修饰方法[J]. 激光与光电子学进展, 2016, 53(8): 082302. Xia Shuzhen, Wang Wenjun, Du Qianqian, Li Shuhong, Zhang Dong, Gao Xuexi, Wang Qingru, Zhang Bingyuan. Anode Modification Method for Improving Light Emission Performance of Organic Light Emitting Diode[J]. Laser & Optoelectronics Progress, 2016, 53(8): 082302.