纳秒激光金属表面着色技术机理研究的发展与展望

高鸿志; 李建美; 霍孟友

应用激光, 2017, 37 (5): 752, 网络出版: 2017-11-24

纳秒激光金属表面着色技术机理研究的发展与展望

Development and Expectation of Coloring Mechanism of Nanosecond Laser on Metal Surface

论文大纲

高鸿志 ^*李建美霍孟友

作者单位

山东大学机械工程学院, 山东济南250061

激光着色钛不锈钢纳秒激光机理 laser coloring Titanium stainless steel nanosecond laser principle

摘要

纳秒激光氧化着色是一种新兴的着色工艺, 不需要专门的涂料, 具有加工灵活、加工精度高等优点。目前纳秒激光氧化着色的技术已经出现很多年, 但尚未在工业应用中得以推广, 原因在于从原理上尚不能完全解释激光照射材料时与材料表面的相互作用, 着色效果上激光参数与产生的颜色之间的定量关系还不明确, 模型与实际效果之间存在差异, 同时该工艺在可重复性、稳定性、加工效率等方面还存在些许的问题需要解决。针以钛金属和不锈钢为例, 对纳秒激光氧化着色的原理进行了阐述, 总结了影响着色效果的因素, 并对该技术所存在的问题进行了总结, 同时讨论了下一步的研究方向。

Abstract

Nanosecond laser oxidation coloring is a new coloring technology, which needs no dye and has the advantages of flexible and high precision. The technology of nanosecond laser oxidation coloring has been used for many years, but it has not been popularized in industrial application in that the interaction between the laser and the material surface can not be fully explained in theory when the laser irradiated material, the quantitative relationship between the laser parameters and the color is not clear, and there is a difference between the model and the actual results. In addition, there are still some problems need to be solved such as repeatability, stability and machining efficiency. The principle of nanosecond laser oxidation coloring is described with Titanium and stainless steel as examples. Several factors affecting the coloring effect and the problems of the technology were summarized, and the next research direction is discussed.

参考文献

[1] ANTONCZAK A J, KOCON D, NOWAK M, et al.Laser-induced colour marking-sensitivity scaling for a stainless steel［J］.Applied Surface Science, 2013, 264(1)：229-236.

[2] LANGLADE C, VANNES A B, KRAFFT J M, et al.Surface modification and tribological behaviour of titanium and titanium alloys after YAG-laser treatments［J］. Surface and Coating Technology, 1998： 383-387.

[3] LAVISSE L, JOUVARD J M, IMHOFF L, et al.Pulsed laser growth and characterization of thin films on titanium substrates［J］.Applied Surface Science, 2007, 253(19)：8226-8230.

[4] PREZ D P A, SERRA P, MORENZA J L.Oxidation of titanium through Nd:YAG laser irradiation［J］.Applied Surface Science, 2002(197-198)：887-890.

[5] LAAKSO P, RUOTSALAINEN S, LEINONEN H, et al.Direct color marking of metals with fiber lasers［R］.VTT-R-02403-09.

[6] ZHENG H Y, LIM G C, WANG X C, et al.Process study for laser-induced surface coloration［J］.Journal of Laser Application, 2002, 14(4)：215-220.

[7] LEHMUSKERO A, KONTTURI V, HILTUNEN J, et al.Modeling of laser-colored stainless steel surfaces by color pixels［J］.Applied Physics B：Lasers and Optics, 2010, 98(2-3)：497-500.

[8] ADAMS D P, MURPHY R D, SAIZ D J, et al.Nanosecond pulsed laser irradiation of titanium：Oxide growth and effects on underlying metal［J］.Surface and Coatings Technology, 2014, 248(15)：38-45.

[9] ADAMS D P, HODGES V C, HIRSCHFELD D A.Nanosecond pulsed laser irradiation of stainless steel 304L：oxide growth and effects on underlying metal［J］.Surf ace and Coatings Technology, 2013, 222(7)：1-8.

[10] PREZ D P A, SERRA P, MORENZA J L.Coloring of titanium by pulsed laser processing in air［J］.Thin Solid Films, 2002, 415(1-2)：201-205.

[11] ANTONCZAK, SKOWRONSKI L, TRZCINSKI M, et al.Laser-induced oxidation of titanium substrate： analysis of the physicochemical structure of the surface and sub-surface layers［J］.Applied Surface Science, 2015, 325：217-226.

[12] AKMAN E, CERKEZOGLU E.Compositional and micro-scratch analyses of laser induced colored surface of titanium［J］.Optics and Lasers in Engineering, 2016, 84：37-43.

[13] SUO Z.Fracture in thin films［M］.［S.l.］：Elsevier Inc., 2001.

[14] VEIKO V, ODINTSOVA G, AGEEV E, et al.Controlled oxide films formation by nanosecond laser pulses for color marking［J］.Optics Express, 2014, 22(20)：24342-24347 .

[15] TAKIKAWA H, MATSUI T, SAKAKIBARA T, et al.Properties of titanium oxide film prepared by reactive cathodic vacuum arc deposition［J］.［s.n.］, 1999, 348(1)：145-151.

[16] TENG K S, DELPLANCKE, J-L.ZHANG J, et al.Electrochemical characterization of copper deposited on plasma and thermally modified titanium surfaces［J］. Metallurgical and Materials Transactions B, 1998, 29(4)：749-754.

[17] LEE J H, JANG G E, JUN Y H.Investigation and evaluation of structural color of TiO2 coating on stainless steel［J］, Ceramics International, 2012, 38：661-664.

[18] DONG H, BELL T.Enhanced wear resistance of titanium surfaces by a new thermal oxidation treatment［J］.Wear, 2000, 238 (2)：131-137.

[19] DIAMANTI M V, DEL C B, PEDEFERRI M.Interference colors of thin oxide layers on titanium［J］.Color Research and Application, 2008, 33(3)： 221-228.

[20] PREZ D P A, FERNNDEZ-PRADAS J M, SERRA P, et al.Coloring of titanium through laser oxidation： comparative study with anodizing［J］. Surface and Coatings Technology, 2004, 187(1)：106-112.

[21] O′HANA S, PINKERTON AJ, SHOBA K, et al.Laser surface colouring of titanium for contemporary jewellery ［J］.［s.n.］, 2008, 24(2)：147-153.

[22] LAVISSE L, GREVEY D, LANGLADE C, et al.The early stage of the laser-induced oxidation of titanium substrates［J］.Applied Surface Science, 2002, 186(1)：150-155.

[23] SKOWRONSKI L, ANTONCZAK A J, TRZCINSKI M, et al.Optical properties of laser induced oxynitride films on titanium［J］.Applied Surface Science, 2014, 304：107-114.

[24] PANJAN M, GUNDE K M, PANJAN P, et al.Designing the color of AlTiN hard coating through interference effect［J］.Surface and Coatings Technology, 2014, 254(10) ：65-72.

[25] LUO F, ONG W, GUAN Y, et al.Study of micro/nanostructures formed by a nanosecond laser in gaseous environments for stainless steel surface coloring［J］.Applied Surface Science, 2015, 328：405-409.

[26] ANTONCZAK A J, STEPAK B, KOZIOL P E, at al.The influence of process parameters on the laser-induced coloring of titanium［J］.Applied Physics A, 2014, 115(3)：1003-1013.

[27] JWAD T, DENG S, BUTT H, et al.Laser induced single spot oxidation of titanium［J］.Applied Surface Science, 2016, 387：617-624.

高鸿志, 李建美, 霍孟友. 纳秒激光金属表面着色技术机理研究的发展与展望[J]. 应用激光, 2017, 37(5): 752. Gao Hongzhi, Li Jianmei, Huo Mengyou. Development and Expectation of Coloring Mechanism of Nanosecond Laser on Metal Surface[J]. APPLIED LASER, 2017, 37(5): 752.

纳秒激光金属表面着色技术机理研究的发展与展望

关于本站 Cookie 的使用提示

全站搜索

纳秒激光金属表面着色技术机理研究的发展与展望

相关论文

相关资讯

关于本站 Cookie 的使用提示

全站搜索